A review of chalcogenide-based perovskites as the next novel materials: Solar cell and optoelectronic applications, catalysis and future perspectives

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Abstract

The increasing demand for renewable energy has stimulated significant advancements in the photovoltaic technology (PV), with perovskite solar cells (PSCs) emerging as leading alternatives because of their impressive efficiency and versatile characteristics. Nevertheless, conventional lead-based PSCs face critical challenges such as environmental instability, lead toxicity, and limited durability, which hinder their broader commercial applications. Chalcogenide-based perovskites, on the other hand have been advanced as promising options, offering improved stability, less toxic compositions, and the potential for more cost-effective, scalable production. This review thoroughly examines the progress made in chalcogenide perovskite research, highlighting their tunable bandgaps for diverse applications, superior charge transport properties, and resilience against advanced weathering conditions such as moisture, oxygen, and UV light. The graphene-like characteristics of certain chalcogenide perovskites, which contribute to their high charge mobility and flexibility, make them strong candidates for the next-generation PV technologies. Furthermore, this work explores the expanding potential for indoor applications of these materials, including their integration into flexible indoor PSCs and other optoelectronic devices designed for controlled environments. Also, various synthesis and optimization strategies, such as advanced deposition techniques, precise doping methods, and innovative interface and additive engineering are presented, aimed at enhancing the PV performance of these materials. Accordingly, this review bridges the gap between fundamental research and practical applications, outlining a strategic direction for developing chalcogenide-based PSCs and optoelectronic devices that meet the global energy demand while advancing sustainability and environmental safety.

综述作为下一代新型材料的卤化物基包晶石:太阳能电池和光电应用、催化和未来展望
对可再生能源日益增长的需求刺激了光伏技术(PV)的重大进步,而过氧化物太阳能电池(PSCs)因其令人印象深刻的效率和多功能特性而成为领先的替代品。然而,传统的铅基 PSCs 面临着环境不稳定性、铅毒性和耐用性有限等严峻挑战,阻碍了其更广泛的商业应用。另一方面,基于钙镓基的过氧化物晶石作为一种有前途的选择,具有更高的稳定性、毒性更低的成分,以及更具成本效益和可扩展生产的潜力。本综述深入探讨了霰化物类包晶石研究取得的进展,重点介绍了它们在各种应用中的可调带隙、优异的电荷传输特性以及对湿气、氧气和紫外线等高级风化条件的适应性。某些掺杂型过氧化物晶石具有类似石墨烯的特性,这有助于实现高电荷迁移率和灵活性,使它们成为下一代光伏技术的有力候选者。此外,这项研究还探讨了这些材料在室内应用方面不断扩大的潜力,包括将它们集成到灵活的室内 PSC 和其他专为受控环境设计的光电设备中。此外,还介绍了各种合成和优化策略,如先进的沉积技术、精确的掺杂方法以及创新的界面和添加剂工程,旨在提高这些材料的光伏性能。因此,本综述在基础研究与实际应用之间架起了一座桥梁,为开发基于卤化镓的 PSC 和光电器件勾勒出了一个战略方向,以满足全球能源需求,同时促进可持续发展和环境安全。
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