{"title":"Synthesis, structural characterization and intense far-red luminescence of Mn4+ -activated SrLaMgTa1-yAlyO6 oxide phosphors","authors":"Jiayue Wu , Yufeng Mao , Jiye Wang, Shikao Shi","doi":"10.1016/j.jlumin.2024.120892","DOIUrl":null,"url":null,"abstract":"<div><p>The transition metal Mn<sup>4+</sup> activated phosphors have attracted increasing attention due to the potential uses in phosphor-converted lighting emitting diodes (LEDs). Herein, the far-red emitting SrLaMgTa<sub>1-y</sub>Al<sub>y</sub>O<sub>6</sub>:Mn<sup>4+</sup> (y = 0−0.15) oxide phosphors were successfully synthesized by the high-temperature solid state reaction, in which the Mn<sup>4+</sup> acted as an activator. The monoclinic double perovskite crystal structure, chemical composition, and 4+ state of activator Mn were confirmed by means of X-ray diffraction Rietveld refinement, scanning electron microscopy elemental mapping, and X-ray photoelectron spectroscopy. The optical properties were characterized with photoluminescence excitation and emission spectra, temperature-dependent emission spectra, and electroluminescence spectra. The excitation spectra are interweaved with the ligand-to-metal charge transfer band of Mn−O and intrinsic transitions (<sup>4</sup>A<sub>2g</sub>→<sup>4</sup>T<sub>1g</sub>, <sup>4</sup>A<sub>2g</sub>→<sup>2</sup>T<sub>2g</sub>, and <sup>4</sup>A<sub>2g</sub>→<sup>4</sup>T<sub>2g</sub>) of Mn<sup>4+</sup>, locating at the ultraviolet and blue light region. The emission spectra mainly contain a dominant far-red emission band from 650 to 775 nm with peaks at 695 and 708 nm, which are ascribed to the <sup>2</sup>E<sub>g</sub>→<sup>4</sup>A<sub>2g</sub> transition of Mn<sup>4+</sup>. Moreover, the cationic substitution strategy with tiny Al<sup>3+</sup> occupying Ta<sup>5+</sup> octahedral site, promotes the improvement of luminescence intensity and optical thermal stability. The quantum yield of optimal phosphor reaches 88.2 % and the fluorescence intensity at 373 K (100 °C) retains 83.4 % in respect to that at ambient temperature, implying the phosphor with intense and thermally stable luminescence. The phosphor is packaged with 365 nm chip to fabricate an LED device, and the electroluminescence result is quite consistent with the photoluminescence, matching well with the absorption spectrum of the phytochrome. The Mn<sup>4+</sup> activated oxide phosphors with intense far-red emission are promising for plant cultivation lighting.</p></div>","PeriodicalId":16159,"journal":{"name":"Journal of Luminescence","volume":"277 ","pages":"Article 120892"},"PeriodicalIF":3.3000,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Luminescence","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022231324004563","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"OPTICS","Score":null,"Total":0}
引用次数: 0
Abstract
The transition metal Mn4+ activated phosphors have attracted increasing attention due to the potential uses in phosphor-converted lighting emitting diodes (LEDs). Herein, the far-red emitting SrLaMgTa1-yAlyO6:Mn4+ (y = 0−0.15) oxide phosphors were successfully synthesized by the high-temperature solid state reaction, in which the Mn4+ acted as an activator. The monoclinic double perovskite crystal structure, chemical composition, and 4+ state of activator Mn were confirmed by means of X-ray diffraction Rietveld refinement, scanning electron microscopy elemental mapping, and X-ray photoelectron spectroscopy. The optical properties were characterized with photoluminescence excitation and emission spectra, temperature-dependent emission spectra, and electroluminescence spectra. The excitation spectra are interweaved with the ligand-to-metal charge transfer band of Mn−O and intrinsic transitions (4A2g→4T1g, 4A2g→2T2g, and 4A2g→4T2g) of Mn4+, locating at the ultraviolet and blue light region. The emission spectra mainly contain a dominant far-red emission band from 650 to 775 nm with peaks at 695 and 708 nm, which are ascribed to the 2Eg→4A2g transition of Mn4+. Moreover, the cationic substitution strategy with tiny Al3+ occupying Ta5+ octahedral site, promotes the improvement of luminescence intensity and optical thermal stability. The quantum yield of optimal phosphor reaches 88.2 % and the fluorescence intensity at 373 K (100 °C) retains 83.4 % in respect to that at ambient temperature, implying the phosphor with intense and thermally stable luminescence. The phosphor is packaged with 365 nm chip to fabricate an LED device, and the electroluminescence result is quite consistent with the photoluminescence, matching well with the absorption spectrum of the phytochrome. The Mn4+ activated oxide phosphors with intense far-red emission are promising for plant cultivation lighting.
期刊介绍:
The purpose of the Journal of Luminescence is to provide a means of communication between scientists in different disciplines who share a common interest in the electronic excited states of molecular, ionic and covalent systems, whether crystalline, amorphous, or liquid.
We invite original papers and reviews on such subjects as: exciton and polariton dynamics, dynamics of localized excited states, energy and charge transport in ordered and disordered systems, radiative and non-radiative recombination, relaxation processes, vibronic interactions in electronic excited states, photochemistry in condensed systems, excited state resonance, double resonance, spin dynamics, selective excitation spectroscopy, hole burning, coherent processes in excited states, (e.g. coherent optical transients, photon echoes, transient gratings), multiphoton processes, optical bistability, photochromism, and new techniques for the study of excited states. This list is not intended to be exhaustive. Papers in the traditional areas of optical spectroscopy (absorption, MCD, luminescence, Raman scattering) are welcome. Papers on applications (phosphors, scintillators, electro- and cathodo-luminescence, radiography, bioimaging, solar energy, energy conversion, etc.) are also welcome if they present results of scientific, rather than only technological interest. However, papers containing purely theoretical results, not related to phenomena in the excited states, as well as papers using luminescence spectroscopy to perform routine analytical chemistry or biochemistry procedures, are outside the scope of the journal. Some exceptions will be possible at the discretion of the editors.