Laser clad CoCrFeNiTixNby hypoeutectic high-entropy alloy coating: Effects of Ti and Nb content on mechanical, wear and corrosion properties

Abstract

High-entropy alloys (HEAs) exhibit significant potential for advanced wear and corrosion-resistant applications. This study investigates the influence of Ti and Nb doping on the microstructure, phase composition, and properties of CoCrFeNiTi_xNb_y HEAs synthesized using high-speed laser cladding (HLC). The results demonstrate that increasing Ti and Nb content transforms the coating structure from a face-centered cubic (FCC) phase to a hybrid structure comprising FCC, body-centered cubic (BCC), and Laves phases, leading to a linear enhancement in surface hardness. The incorporation of Ti and Nb not only promotes the preferred orientation of the FCC phase (111) crystal plane but also significantly enhances tensile strength, though this comes at the expense of reduced plasticity. Specifically, the CoCrFeNiTi_0.6Nb_0.15 coating attains an ideal balance between strength and ductility, with a tensile strength of 1641.8 MPa and a tensile strain of 15.9 %, achieved through the formation of a eutectic structure. This coating also exhibits superior wear resistance and outstanding corrosion resistance, which are attributed to the stability of the passivation film, reinforced by the (111) crystal plane and high-density dislocations. These findings provide both theoretical and empirical foundations for the design of high-performance HEAs, underscoring their potential in industrial applications requiring robust wear and corrosion resistance.