{"title":"Yttrium-based metal-organic frameworks built on hexanuclear clusters","authors":"Shenfang Li, Tao Shen, Manglai Gao, Hao Wang","doi":"10.1039/d4dt01658k","DOIUrl":null,"url":null,"abstract":"Yttrium-based metal-organic frameworks built on hexanuclear clusters (Y6-MOFs) represent an important subgroup of MOFs that are assembled from Y6 clusters and diverse organic linkers, featuring a variety of topologies. Due to the robust Y-O bonds and high connectivity of hexanuclear SBUs, Y6-MOFs are generally thermally stable and resistant to water. Additionally, their pore structures are highly tunable through the practice of reticular chemistry strategy, resulting in excellent performance in gas adsorption and separation related applications. Y6-MOFs are structurally analogous to Zr6-MOFs; however, the existence of charge-balancing cations in Y6-MOFs serves as an additional pore structure regulator, enhancing their tailorability with respect to pore shape and dimensions. In this Frontier article, we summarize the main advances in the design and synthesis of Y6-MOFs, with a particular focus on the precise engineering of their pore structure for gas separations. Future directions of research efforts in this field are also discussed.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":null,"pages":null},"PeriodicalIF":3.5000,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4dt01658k","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Yttrium-based metal-organic frameworks built on hexanuclear clusters (Y6-MOFs) represent an important subgroup of MOFs that are assembled from Y6 clusters and diverse organic linkers, featuring a variety of topologies. Due to the robust Y-O bonds and high connectivity of hexanuclear SBUs, Y6-MOFs are generally thermally stable and resistant to water. Additionally, their pore structures are highly tunable through the practice of reticular chemistry strategy, resulting in excellent performance in gas adsorption and separation related applications. Y6-MOFs are structurally analogous to Zr6-MOFs; however, the existence of charge-balancing cations in Y6-MOFs serves as an additional pore structure regulator, enhancing their tailorability with respect to pore shape and dimensions. In this Frontier article, we summarize the main advances in the design and synthesis of Y6-MOFs, with a particular focus on the precise engineering of their pore structure for gas separations. Future directions of research efforts in this field are also discussed.
期刊介绍:
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.