Antonis Anastassiades, Dimitris I. Alexandropoulos, Christian D. Buch, Stergios Piligkos, Anastasios Tasiopoulos
{"title":"A New Family of Heterometallic [Cu6M4] (M = Gd, Tb, Dy and Y) Clusters Derived from the Combined use of Selected Pyridyl Poly-alcohol Ligands","authors":"Antonis Anastassiades, Dimitris I. Alexandropoulos, Christian D. Buch, Stergios Piligkos, Anastasios Tasiopoulos","doi":"10.1039/d4dt02054e","DOIUrl":null,"url":null,"abstract":"The combined use of 2-(2-pyridyl)-1,3-propane-diol (pypdH2) and 2-hydroxymethyl-2-(2-pyridyl)-1,3-propane-diol (pyptH3) in Cu2+/4f chemistry has afforded a new family of isostructural [Cu6M4(pypt)4(pypdH)4(NO3)8] [M = Gd (1), Tb (2), Dy (3), and Y (4)] complexes. These compounds are based on an unprecedented three-layered symmetric [Cu6M4(μ-ΟR)16]8+ structural core, formed from the connection of the metal ions by bridging alkoxide arms of the organic ligands. Direct current magnetic susceptibility studies for complexes 1 - 3 revealed the presence of dominant ferromagnetic exchange interactions, suggesting the existence of large spin ground state values. Alternating current magnetic studies indicate the presence of slow-magnetic relaxation in 1 - 3.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":null,"pages":null},"PeriodicalIF":3.5000,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4dt02054e","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The combined use of 2-(2-pyridyl)-1,3-propane-diol (pypdH2) and 2-hydroxymethyl-2-(2-pyridyl)-1,3-propane-diol (pyptH3) in Cu2+/4f chemistry has afforded a new family of isostructural [Cu6M4(pypt)4(pypdH)4(NO3)8] [M = Gd (1), Tb (2), Dy (3), and Y (4)] complexes. These compounds are based on an unprecedented three-layered symmetric [Cu6M4(μ-ΟR)16]8+ structural core, formed from the connection of the metal ions by bridging alkoxide arms of the organic ligands. Direct current magnetic susceptibility studies for complexes 1 - 3 revealed the presence of dominant ferromagnetic exchange interactions, suggesting the existence of large spin ground state values. Alternating current magnetic studies indicate the presence of slow-magnetic relaxation in 1 - 3.
期刊介绍:
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.