Synergistic catalytic effects of combined manganese-based driers on accelerating the drying process of tung oil

IF 6.5 2区材料科学 Q1 CHEMISTRY, APPLIED

Progress in Organic Coatings Pub Date : 2024-09-09 DOI:10.1016/j.porgcoat.2024.108792

{"title":"Synergistic catalytic effects of combined manganese-based driers on accelerating the drying process of tung oil","authors":"","doi":"10.1016/j.porgcoat.2024.108792","DOIUrl":null,"url":null,"abstract":"<div>Although manganese-based driers with nitrogen- or oxygen-containing ligands can accelerate the surface drying of tung oil film, their mechanical property performance does not meet industrial requirements. To address this, the drying activities of manganese-based driers with nitrogen- and oxygen-containing ligands on tung oil film were investigated. The curing process of tung oil film catalyzed by the combination driers of Mn(OH)2(benz)2·Mn(H2O)2(acac)2, MnCl2(bipy)2·Mn(H2O)2(acac)2, and MnCl2(bipy)2·Mn(OH)2(benz)2 was revealed using Fourier-transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). The results revealed that the combination driers enhanced the drying activities of Mn2+ in tung oil due to a synergistic effect between Mn2+ and its ligands. This process catalyzed the crosslinking of tung oil, giving the tung oil film a faster drying time, greater scratch resistance, increased hardness, improved flexibility, and greater thermal stability. These materials may replace traditional heavy metal driers to produce tung oil films with outstanding mechanical properties. Additionally, this paper describes the drying mechanism of these manganese-based driers with a combination of nitrogen-containing and oxygen-containing ligands and provides a new tung oil drying method.</div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":null,"pages":null},"PeriodicalIF":6.5000,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Organic Coatings","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0300944024005848","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}

引用次数: 0

Abstract

Although manganese-based driers with nitrogen- or oxygen-containing ligands can accelerate the surface drying of tung oil film, their mechanical property performance does not meet industrial requirements. To address this, the drying activities of manganese-based driers with nitrogen- and oxygen-containing ligands on tung oil film were investigated. The curing process of tung oil film catalyzed by the combination driers of Mn(OH)₂(benz)₂·Mn(H₂O)₂(acac)₂, MnCl₂(bipy)₂·Mn(H₂O)₂(acac)₂, and MnCl₂(bipy)₂·Mn(OH)₂(benz)₂ was revealed using Fourier-transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). The results revealed that the combination driers enhanced the drying activities of Mn²⁺ in tung oil due to a synergistic effect between Mn²⁺ and its ligands. This process catalyzed the crosslinking of tung oil, giving the tung oil film a faster drying time, greater scratch resistance, increased hardness, improved flexibility, and greater thermal stability. These materials may replace traditional heavy metal driers to produce tung oil films with outstanding mechanical properties. Additionally, this paper describes the drying mechanism of these manganese-based driers with a combination of nitrogen-containing and oxygen-containing ligands and provides a new tung oil drying method.

Abstract Image

查看原文本刊更多论文

锰基联合干燥剂对加速桐油干燥过程的协同催化作用

虽然含氮或含氧配体的锰基干燥剂可以加速桐油薄膜的表面干燥，但其机械性能却不能满足工业要求。为此，研究了含氮和含氧配体的锰基干燥剂对桐油薄膜的干燥活性。在 Mn(OH)2(benz)2-Mn(H2O)2(acac)2、MnCl2(bipy)2-Mn(H2O)2(acac)2 和 MnCl2(bipy)2-Mn(H2O)2(acac)2 组合干燥剂的催化下，桐油薄膜的固化过程发生了变化、和 MnCl2(bipy)2-Mn(OH)2(benz)2。结果表明，由于 Mn2+ 及其配体之间的协同作用，组合干燥剂增强了 Mn2+ 在桐油中的干燥活性。这一过程催化了桐油的交联，使桐油膜具有更快的干燥时间、更强的抗划伤性、更高的硬度、更好的柔韧性和更高的热稳定性。这些材料可以取代传统的重金属干燥剂，生产出具有出色机械性能的桐油薄膜。此外，本文还介绍了这些含氮和含氧配体组合的锰基干燥剂的干燥机理，并提供了一种新的桐油干燥方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Progress in Organic Coatings 工程技术-材料科学：膜

CiteScore

11.40

自引率

15.20%

发文量

577

审稿时长

48 days

期刊介绍： The aim of this international journal is to analyse and publicise the progress and current state of knowledge in the field of organic coatings and related materials. The Editors and the Editorial Board members will solicit both review and research papers from academic and industrial scientists who are actively engaged in research and development or, in the case of review papers, have extensive experience in the subject to be reviewed. Unsolicited manuscripts will be accepted if they meet the journal''s requirements. The journal publishes papers dealing with such subjects as: • Chemical, physical and technological properties of organic coatings and related materials • Problems and methods of preparation, manufacture and application of these materials • Performance, testing and analysis.