Capacitance Measurement for Evaluating the Initial Top-Electrode-Damage-Induced Degradation of Organic Devices

IF 11.3 1区 化学 Q1 CHEMISTRY, PHYSICAL
Chunqin Zhu, Guangrui Zhu, Ya Zhao, Ruichen Yi, Xiaoyuan Hou and Jiajun Qin*, 
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Abstract

The formation of bubbles and fractures on the top electrode surface is one of the key factors that leads to the degradation of organic devices. This degradation can be directly observed through optical microscopy but only in low spatial resolution of several micrometers due to limited optical contrast between the bubbles and their surroundings. Here, we present a nonintrusive capacitance method to characterize electrode damage with improved accuracy and testing efficiency. For serious degradation with a large damage area at the top electrode (almost more than 10 μm), the relative drop in capacitance after degradation is consistent with the results derived by optical microscopy. For initial degradation with a damage area below the resolution of optical microscopy (even less than 1 μm), our proposed capacitance method still works well, which is validated by atomic force microscopy results.

Abstract Image

电容测量用于评估有机器件顶部电极损坏引起的初始降解
顶部电极表面气泡和裂缝的形成是导致有机器件降解的关键因素之一。这种降解可以通过光学显微镜直接观察到,但由于气泡及其周围环境之间的光学对比度有限,因此空间分辨率很低,只有几微米。在此,我们提出了一种非侵入式电容方法,用于表征电极损伤,提高了准确性和测试效率。对于顶部电极损坏面积较大(几乎超过 10 μm)的严重降解,降解后电容的相对下降与光学显微镜得出的结果一致。对于损伤面积低于光学显微镜分辨率(甚至小于 1 μm)的初始降解,我们提出的电容计算方法仍然有效,原子力显微镜的结果也验证了这一点。
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来源期刊
ACS Catalysis
ACS Catalysis CHEMISTRY, PHYSICAL-
CiteScore
20.80
自引率
6.20%
发文量
1253
审稿时长
1.5 months
期刊介绍: ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels. The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.
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