SnO2-TiO2 materials for photocatalytic degradation of cationic dye under UV and visible light and a chitosan composite film investigation

Abstract

The possibility of SnO₂ incorporation and immobilization as films forming composites opens new perspectives for TiO₂ to profit visible light and to facilitate the photocatalytic process, respectively. In this study, 0 %, 1 % and 10 % wt. of SnO₂ was incorporated into TiO₂ (SnO₂-TiO₂) by coprecipitation in a sol-gel method by ammonia addition, followed for calcination at 500 °C. The photocatalysts were characterized by N₂ adsorption-desorption, FTIR spectroscopy, XRD Rietveld refinement, TG-DTG, SEM-EDS, DRS and elemental analysis. The performance of all solids was evaluated in the photocatalytic degradation of the cationic dye methylene blue in aqueous phase, under visible and UV irradiation, at 25 °C for 2 h. The results showed that the incorporation of Sn into TiO₂ improved the textural properties and decreased the bandgap. All solids presented only TiO₂ typical diffractograms, with anatase as the main phase, but catalyst with 10 % SnO₂ presented also brookite phase, inferring that Sn atoms were incorporated into TiO₂ structure, corroborated by MEV results. All tin-based photocatalysts show high activity under UV and visible light, with the 10 % SnO₂ material reaching 83 % and 88 % degradation after 2 h under UV and visible radiation, respectively. This material was tested as an immobilized film, achieving 14 % of decolorization, and the reuse was also evaluated. Our investigation demonstrates that SnO₂-TiO₂ catalysts could be used to decompose a dye under UV and Visible light as powder in a batch reactor and immobilized as a composite film with chitosan, that opens new perspectives to facilitate the application using solar light.