Erosion characteristics analysis of molybdenum grid in ion thrusters based on optical emission spectroscopy method and actinometry

IF 3.2 2区 化学 Q1 SPECTROSCOPY
Xi-Ming Zhu , Bo-Wen Zheng , Wei Xi , Yan-Fei Wang , Yong-Qi Kang , Da-Ren Yu
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Abstract

Optical emission spectroscopy (OES) method is a powerful technique to identify the components of species in the plasma and obtain density based on actinometry. The key component of high-precision and long lifetime aerospace device, such as the grid of ion thruster, is usually made up by erosion-resistant materials, resulting in an extremely low density of erosion product. But the information on these erosion processes is indispensable to optimize the design of those components. The traditional method used to evaluate the erosion process mainly depends on measuring the depth of erosion, while it is a process that necessitates the accumulation of at least hundreds of hours. So, the traditional way is incapable of measuring in multiple working condition and cannot provide online monitoring. Considering this dilemma, this work demonstrates an advanced actinometry based on OES method to analyze the Mo atoms generated during the working process of ion thruster, with more specific atomic emission lines of working gas and product used than the traditional method. The result of this work indicates that the Mo atoms at trace level can be detected successfully, and the concentration of Mo atoms can also be determined based on the advanced actinometry. The result obtained in this work also reveals more intricate relationship between erosion characteristics and various operational parameters, indicating that OES method and advanced actinometry can be used for evaluating the erosion characteristics of aerospace device in different working conditions in a real-time and efficient way, which plays a vital role in deep space exploration and gravitational wave detection by contributing lifetime optimization designs of those devices.

Abstract Image

基于光学发射光谱法和辐射测量法的离子推进器钼栅腐蚀特性分析
光学发射光谱(OES)方法是一种基于动量法识别等离子体中物种成分并获得密度的强大技术。高精度、长寿命航空航天设备的关键部件,如离子推进器的栅格,通常由抗侵蚀材料构成,因此侵蚀产物的密度极低。但要优化这些部件的设计,有关这些侵蚀过程的信息是必不可少的。用于评估侵蚀过程的传统方法主要依靠测量侵蚀深度,而这一过程需要至少数百小时的积累。因此,传统方法无法在多种工况下进行测量,也无法提供在线监测。考虑到这一难题,这项工作展示了一种基于 OES 方法的先进放电测量法,用于分析离子推进器工作过程中产生的 Mo 原子,与传统方法相比,所使用的工作气体和产品的原子发射线更为具体。这项工作的结果表明,可以成功地检测到痕量水平的钼原子,而且还可以根据先进的放电法测定钼原子的浓度。这项工作所获得的结果还揭示了侵蚀特性与各种运行参数之间更为复杂的关系,表明 OES 方法和先进的放电法可用于实时、高效地评估航空航天装置在不同工作条件下的侵蚀特性,这将有助于这些装置的寿命优化设计,从而在深空探测和引力波探测中发挥重要作用。
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来源期刊
CiteScore
6.10
自引率
12.10%
发文量
173
审稿时长
81 days
期刊介绍: Spectrochimica Acta Part B: Atomic Spectroscopy, is intended for the rapid publication of both original work and reviews in the following fields: Atomic Emission (AES), Atomic Absorption (AAS) and Atomic Fluorescence (AFS) spectroscopy; Mass Spectrometry (MS) for inorganic analysis covering Spark Source (SS-MS), Inductively Coupled Plasma (ICP-MS), Glow Discharge (GD-MS), and Secondary Ion Mass Spectrometry (SIMS). Laser induced atomic spectroscopy for inorganic analysis, including non-linear optical laser spectroscopy, covering Laser Enhanced Ionization (LEI), Laser Induced Fluorescence (LIF), Resonance Ionization Spectroscopy (RIS) and Resonance Ionization Mass Spectrometry (RIMS); Laser Induced Breakdown Spectroscopy (LIBS); Cavity Ringdown Spectroscopy (CRDS), Laser Ablation Inductively Coupled Plasma Atomic Emission Spectroscopy (LA-ICP-AES) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). X-ray spectrometry, X-ray Optics and Microanalysis, including X-ray fluorescence spectrometry (XRF) and related techniques, in particular Total-reflection X-ray Fluorescence Spectrometry (TXRF), and Synchrotron Radiation-excited Total reflection XRF (SR-TXRF). Manuscripts dealing with (i) fundamentals, (ii) methodology development, (iii)instrumentation, and (iv) applications, can be submitted for publication.
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