{"title":"Exergetic efficiency and CO2 intensity of hydrogen supply chain including underground storage","authors":"Boyukagha Baghirov , Denis Voskov , Rouhi Farajzadeh","doi":"10.1016/j.ecmx.2024.100695","DOIUrl":null,"url":null,"abstract":"<div><p>Hydrogen plays a crucial role in the transition to low-carbon energy systems, especially when integrated into energy storage applications. In this study, the concept of exergy-return on exergy-investment (ERoEI) is applied to investigate the exergetic efficiency (defined as the ratio of useful exergy output to invested exergy input) and CO<sub>2</sub> equivalent intensity of the hydrogen supply chain, with a specific focus on the underground hydrogen storage process. Our findings reveal that the overall exergetic efficiency of the electricity-to-hydrogen-to-electricity conversion process can reach up to 25 %. Among the hydrogen production methods, green hydrogen, produced via electrolysis powered by renewable energy, exhibits the lowest CO<sub>2</sub> equivalent intensity. Blue hydrogen, produced from natural gas with carbon capture, can significantly reduce the carbon footprint of electricity generation, though this advantage comes at the expense of decreased exergetic efficiency. Analysis further indicates that the exergetic efficiency of underground storage components ranges from 72 % to 92 %. A substantial fraction of the exergy is lost during compression and injection of the stored hydrogen. Nevertheless, the subsurface operations contribute a minimal CO<sub>2</sub> emission, between 1.46–4.56 grams of equivalent CO<sub>2</sub> per megajoule (gr-CO<sub>2eq</sub>/MJ) when powered by low-carbon energy sources. Furthermore, it is found that hydrogen loss in the reservoir, along with methane and hydrogen leak during surface operations, notably affects the overall efficiency of the storage process.</p></div>","PeriodicalId":37131,"journal":{"name":"Energy Conversion and Management-X","volume":"24 ","pages":"Article 100695"},"PeriodicalIF":7.1000,"publicationDate":"2024-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2590174524001739/pdfft?md5=f1f3ac2bdeea68081e3741cf51d08bc9&pid=1-s2.0-S2590174524001739-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy Conversion and Management-X","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2590174524001739","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
Hydrogen plays a crucial role in the transition to low-carbon energy systems, especially when integrated into energy storage applications. In this study, the concept of exergy-return on exergy-investment (ERoEI) is applied to investigate the exergetic efficiency (defined as the ratio of useful exergy output to invested exergy input) and CO2 equivalent intensity of the hydrogen supply chain, with a specific focus on the underground hydrogen storage process. Our findings reveal that the overall exergetic efficiency of the electricity-to-hydrogen-to-electricity conversion process can reach up to 25 %. Among the hydrogen production methods, green hydrogen, produced via electrolysis powered by renewable energy, exhibits the lowest CO2 equivalent intensity. Blue hydrogen, produced from natural gas with carbon capture, can significantly reduce the carbon footprint of electricity generation, though this advantage comes at the expense of decreased exergetic efficiency. Analysis further indicates that the exergetic efficiency of underground storage components ranges from 72 % to 92 %. A substantial fraction of the exergy is lost during compression and injection of the stored hydrogen. Nevertheless, the subsurface operations contribute a minimal CO2 emission, between 1.46–4.56 grams of equivalent CO2 per megajoule (gr-CO2eq/MJ) when powered by low-carbon energy sources. Furthermore, it is found that hydrogen loss in the reservoir, along with methane and hydrogen leak during surface operations, notably affects the overall efficiency of the storage process.
期刊介绍:
Energy Conversion and Management: X is the open access extension of the reputable journal Energy Conversion and Management, serving as a platform for interdisciplinary research on a wide array of critical energy subjects. The journal is dedicated to publishing original contributions and in-depth technical review articles that present groundbreaking research on topics spanning energy generation, utilization, conversion, storage, transmission, conservation, management, and sustainability.
The scope of Energy Conversion and Management: X encompasses various forms of energy, including mechanical, thermal, nuclear, chemical, electromagnetic, magnetic, and electric energy. It addresses all known energy resources, highlighting both conventional sources like fossil fuels and nuclear power, as well as renewable resources such as solar, biomass, hydro, wind, geothermal, and ocean energy.