Decolorization of RhB on three-dimensional porous CeO2/LaFeO3/SrTiO3 catalyst via photo-fenton-like catalysis.

IF 2.7 3区 化学 Q3 BIOCHEMISTRY & MOLECULAR BIOLOGY
Photochemical & Photobiological Sciences Pub Date : 2024-09-01 Epub Date: 2024-08-26 DOI:10.1007/s43630-024-00619-1
Lihua Zhang, Guowen Dong, Xiaomin Liu, Yu Niu, Wei Gao, Qiong Yang, Zaixing Li
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引用次数: 0

Abstract

The catalysts with three-dimensional porous (3DP) CeO2, LaFeO3 and SrTiO3 are synthesized by sol-gel method and chemical precipitation method. The resulting multi-component 3DP CeO2/LaFeO3/SrTiO3 composite material featured a high specific surface area (26.08 m2/g), which can provide more surface active sites to improve adsorption capacity and catalytic performance. The photocatalytic, Fenton-like, photo-Fenton-like performance of the catalyst are studied on decolorization of RhB under UV irradiation, respectively. 3DP CeO2/LaFeO3/SrTiO3 exhibits high catalytic performance. Compared with photocatalytic or Fenton-like performance, 3DP CeO2/LaFeO3/SrTiO3 catalyst exhibits higher photo-Fenton-like performance, facilitating efficient decolorization of the rhodamine B. Moreover, the initial reaction rate on decolorization of RhB with 3DP CeO2/LaFeO3/SrTiO3 is 10.55, 5.52, 3.67 and 1.51 times higher than that with SrTiO3, LaFeO3, 3DP CeO2 and 3DP CeO2/LaFeO3, respectively. Meanwhile, 3DP LaFeO3/CeO2/SrTiO3 has a wider pH usage range in the synergistic reaction. Finally, a catalytic mechanism for the decolorization of rhodamine B is proposed. The continuous cycling of Fe3+/Fe2+ and Ce4+/Ce3+ and the production of active substances are achieved under the photo-Fenton-like effect of the catalyst.

Abstract Image

在三维多孔 CeO2/LaFeO3/SrTiO3 催化剂上通过类光芬顿催化实现 RhB 的脱色。
采用溶胶-凝胶法和化学沉淀法合成了三维多孔(3DP)CeO2、LaFeO3 和 SrTiO3 催化剂。所得到的多组分 3DP CeO2/LaFeO3/SrTiO3 复合材料具有较高的比表面积(26.08 m2/g),可以提供更多的表面活性位点,从而提高吸附能力和催化性能。分别研究了催化剂在紫外照射下对 RhB 脱色的光催化性能、Fenton 类性能和光 Fenton 类性能。3DP CeO2/LaFeO3/SrTiO3 表现出很高的催化性能。与光催化或类 Fenton 性能相比,3DP CeO2/LaFeO3/SrTiO3 催化剂具有更高的类 Fenton 光催化性能,有助于罗丹明 B 的高效脱色。此外,3DP CeO2/LaFeO3/SrTiO3 对罗丹明 B 的脱色初始反应速率分别是 SrTiO3、LaFeO3、3DP CeO2 和 3DP CeO2/LaFeO3 的 10.55、5.52、3.67 和 1.51 倍。同时,3DP LaFeO3/CeO2/SrTiO3 在协同反应中具有更宽的 pH 值使用范围。最后,提出了罗丹明 B 脱色的催化机理。在催化剂的光-芬顿效应下,实现了 Fe3+/Fe2+ 和 Ce4+/Ce3+ 的连续循环以及活性物质的产生。
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来源期刊
Photochemical & Photobiological Sciences
Photochemical & Photobiological Sciences 生物-生化与分子生物学
CiteScore
5.60
自引率
6.50%
发文量
201
审稿时长
2.3 months
期刊介绍: A society-owned journal publishing high quality research on all aspects of photochemistry and photobiology.
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