Investigation of polymeric organofluorosilicates and organofluorogermanates

IF 1.7 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Fluorine Chemistry Pub Date : 2024-08-01 DOI:10.1016/j.jfluchem.2024.110332

Jan Gnidovec , Gašper Tavčar

引用次数: 0

Abstract

The reactions of representative organochlorosilanes and organochlorogermanes with alkali metal fluorides (LiF, NaF, KF, RbF, CsF) were investigated by NMR spectroscopy and showed not only the fluorination to organofluorosilanes or organofluorogermanes but also the formation of organofluorosilicates and organofluorogermanates. The synthesis and crystal structures of two new polymeric organofluorogermanates, [K][Ph₂GeF₃]∙0.75 MeCN and [Cs][Ph₂GeF₃]∙THF, are presented.

Abstract Image

查看原文本刊更多论文

研究聚合有机氟硅酸盐和有机氟锗酸盐

利用核磁共振光谱研究了代表性有机氯硅烷和有机氯锗与碱金属氟化物（LiF、NaF、KF、RbF、CsF）的反应，结果表明不仅氟化成了有机氟硅烷或有机氟锗，而且形成了有机氟硅酸盐和有机氟锗酸盐。本文介绍了[K][Ph2GeF3]∙0.75 MeCN 和[Cs][Ph2GeF3]∙THF 这两种新型聚合物有机氟锗酸盐的合成和晶体结构。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Fluorine Chemistry 化学-无机化学与核化学

CiteScore

3.80

自引率

10.50%

发文量

审稿时长

33 days

期刊介绍： The Journal of Fluorine Chemistry contains reviews, original papers and short communications. The journal covers all aspects of pure and applied research on the chemistry as well as on the applications of fluorine, and of compounds or materials where fluorine exercises significant effects. This can include all chemistry research areas (inorganic, organic, organometallic, macromolecular and physical chemistry) but also includes papers on biological/biochemical related aspects of Fluorine chemistry as well as medicinal, agrochemical and pharmacological research. The Journal of Fluorine Chemistry also publishes environmental and industrial papers dealing with aspects of Fluorine chemistry on energy and material sciences. Preparative and physico-chemical investigations as well as theoretical, structural and mechanistic aspects are covered. The Journal, however, does not accept work of purely routine nature. For reviews and special issues on particular topics of fluorine chemistry or from selected symposia, please contact the Regional Editors for further details.