Laser Sintering Direct Ink Write Silver Nanoflake Ink for On-Demand Manufacturing of Electronics in Space

Ellie Schlake;Nirmala Kandadai
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Abstract

Developing manufacturing methods for flexible electronics will enable and improve the large-scale production of flexible, spatially efficient, and lightweight devices. Laser sintering is a promising postprocessing method to produce consolidated films for flexible electronic devices while reducing power consumption compared to standard thermal sintering. This work further explores laser sintering of direct ink write (nScrypt) printed silver as a continuation of previous studies on nScrypt-printed silver and aerosol jet-printed gold, platinum, and titanium dioxide for manufacturing printed electronics (PEs) on the International Space Station (ISS). Four different laser wavelengths are studied for laser sintering nScrypt silver nanoflake ink on flexible polyimide and rigid glass substrates. The laser systems investigated are continuous wave (CW) 808 nm, CW 445 nm, CW 1064 nm, and pulsed femtosecond (fs) 1040-nm lasers. The laser power and scanning speed are varied to compare the laser systems and optimize laser sintering parameters for the silver ink. The resistivity of the laser-sintered silver NPs is compared to the resistivity of the unsintered silver to demonstrate the effectiveness of laser sintering. An optimal resistivity of $5.81\times 10^{-8}\,\,\Omega \cdot \text{m}$ is achieved for the nScrypt silver laser sintered using a fs 1040-nm laser.
用于按需制造太空电子产品的激光烧结直接写入纳米银墨水
开发柔性电子设备的制造方法将有助于大规模生产柔性、空间效率高和重量轻的设备。与标准热烧结法相比,激光烧结法是一种很有前途的后处理方法,可用于生产柔性电子设备的固化薄膜,同时降低功耗。本研究进一步探索了激光烧结直接墨水写入(nScrypt)印刷银的方法,这是对之前关于 nScrypt 印刷银和气溶胶喷射印刷金、铂和二氧化钛的研究的延续,用于在国际空间站(ISS)上制造印刷电子器件(PE)。研究了四种不同波长的激光,用于在柔性聚酰亚胺和硬质玻璃基底上激光烧结 nScrypt 纳米银墨。所研究的激光系统包括连续波 (CW) 808 nm、CW 445 nm、CW 1064 nm 和脉冲飞秒 (fs) 1040 nm 激光。通过改变激光功率和扫描速度来比较各种激光系统,并优化银墨的激光烧结参数。将激光烧结银 NP 的电阻率与未烧结银的电阻率进行比较,以证明激光烧结的有效性。使用fs 1040-nm激光烧结的nScrypt银的最佳电阻率为5.81times 10^{-8}\,\,\Omega\cdot\text{m}$。
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