The fascinating world of polymer crystal hydrates: An overview

IF 3.5 3区 工程技术 Q2 ENGINEERING, CHEMICAL
AIChE Journal Pub Date : 2024-08-16 DOI:10.1002/aic.18556
Dominick Filonowich, Sachin Velankar, John A. Keith
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引用次数: 0

Abstract

Polymer crystal hydrates (PCHs) are crystalline solids that form between a polymer and water. To date, only four distinct PCHs have been discovered—one of polyoxacyclobutane (POCB) and water, and three different polymorphs of polyethyleneimine (PEI) and water. These PCHs were first reported decades ago and have fascinating structures and peculiar properties that make them potentially useful for a wide range of applications including refrigeration, proton conduction membranes, and desalination. This perspective revisits what is known about these compounds, categorizes their similarities and differences with other known compounds, and offers a perspective into future efforts to discover new PCHs to address technological needs for society.

Abstract Image

聚合物晶体水合物的迷人世界:概述
聚合物晶体水合物(PCH)是聚合物与水之间形成的结晶固体。迄今为止,只发现了四种不同的 PCH--一种是聚氧乙烯环丁烷(POCB)和水,另一种是聚乙烯亚胺(PEI)和水的三种不同多晶体。这些 PCH 早在几十年前就被首次报道,它们具有迷人的结构和奇特的性质,可用于制冷、质子传导膜和海水淡化等广泛领域。本视角重新审视了人们对这些化合物的了解,对它们与其他已知化合物的异同进行了分类,并对未来发现新的 PCH 以满足社会技术需求的努力进行了展望。
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来源期刊
AIChE Journal
AIChE Journal 工程技术-工程:化工
CiteScore
7.10
自引率
10.80%
发文量
411
审稿时长
3.6 months
期刊介绍: The AIChE Journal is the premier research monthly in chemical engineering and related fields. This peer-reviewed and broad-based journal reports on the most important and latest technological advances in core areas of chemical engineering as well as in other relevant engineering disciplines. To keep abreast with the progressive outlook of the profession, the Journal has been expanding the scope of its editorial contents to include such fast developing areas as biotechnology, electrochemical engineering, and environmental engineering. The AIChE Journal is indeed the global communications vehicle for the world-renowned researchers to exchange top-notch research findings with one another. Subscribing to the AIChE Journal is like having immediate access to nine topical journals in the field. Articles are categorized according to the following topical areas: Biomolecular Engineering, Bioengineering, Biochemicals, Biofuels, and Food Inorganic Materials: Synthesis and Processing Particle Technology and Fluidization Process Systems Engineering Reaction Engineering, Kinetics and Catalysis Separations: Materials, Devices and Processes Soft Materials: Synthesis, Processing and Products Thermodynamics and Molecular-Scale Phenomena Transport Phenomena and Fluid Mechanics.
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