Study on main sources of aerosol pH and new methods for additional reduction of PM2.5 during winter severe pollution: Based on the PMF-GAS model

Abstract

In recent years, the air quality in urban areas of China has been a significant improvement. However, further advancements in air quality remain challenging, particularly in addressing the persistent problem of severe particulate matter (PM) pollution in winter. In-depth research on the aerosol acidity (pH) is beneficial for analyzing the pollution characteristics of PM and providing support for the continuous improvement of PM pollution. In this study, the sources of water-soluble inorganic ions (WSIIs) of PM_2.5 in Zhengzhou were analyzed based on the PMF-GAS method, and the contribution of different sources to aerosol acidity was further investigated in conjunction with the ISORROPIA-II thermodynamic model. The research results indicate that secondary aerosols are the main source, and controlling the emissions of secondary aerosols and gaseous precursors is a crucial measure for reducing PM_2.5 concentrations. Furthermore, the study revealed that targeted reductions of major pollution sources across varying pH ranges could significantly lower PM_2.5 concentrations. In the range of pH < 4, when the contribution of secondary aerosol source is 23.9%, PM_2.5 concentrations can be reduced by 40.6%, resulting in an additional emission reduction of 5.9 μg m⁻³. In the range of 4 < pH < 6, PM_2.5 can be reduced by 36.9% at a contribution of 16.5% from secondary aerosol source, achieving an additional emission reduction of 7.0 μg m⁻³. This research provides important theoretical support for gaining a deeper understanding of the sources and control of atmospheric pollution, offering strategies to expedite the achievement of PM_2.5 standards and further mitigating its impacts on human health and the environment.