Sustainability and durability performance evaluation of geopolymer concrete with industrial effluent as alternative to conventional river sand

Abstract

Due to infrastructural development activities, the need for the construction materials increases, because of which most of the naturally available natural resources are over exploited and the cost of construction materials are increased. Therefore, the present study focuses on the use of industrial by-products for the development of concrete and examines the physical, mechanical, durability and sustainable performances. Fly ash (FA) and ground granulated blast furnace slag (GGBS) were employed as binder medium and the industrial effluent sodium silicate waste was used to replace the conventional river sand in the geopolymer concrete (GPC). GGBS was employed as source material for the production of concrete to increase the polymerization reaction process and further, the developed concrete was cured in the ambient condition of temperature range 27 ± 2 °C, in the laboratory. The concentration of the sodium hydroxide (NaOH) in the present study was 12M, and the alkaline solution ratio was 1:1.5. During the production process of sodium silicate solution in the factory, the residue left at the bottom of the boiling hopper were dumped as waste in the open land. GPC gains its strength based on the alumina and silica in the source material and alkaline activator solution, therefore, this industrial waste residue was identified as potential alternative to conventional river sand. The concrete with and without effluent was subjected to two types of acid (Sulfuric acid (H₂SO₄) and Hydrochloric acid (HCl)) and further to examine the performance of concrete under marine condition, two types of salt solutions, namely, magnesium sulfate (MgSO₄) and Sodium Chloride (NaCl) were used, the concentration of acids employed in the present study is 2% and the marine solution is 3.5%. Increase in the proportion of effluent from 0% to 100% decreases the slump value of the concrete. Contrastingly, increasing the proportion of effluent increases the strength of GPC after 28-d of room temperature curing. To examine the performance of the concrete under acidic and marine conditions, average of three concrete specimens were employed and the duration of exposure was considered in the present study starts from 28-d and continues till 360-d. After exposing to acidic environment, mass loss, strength loss and surface modification were examined; the loss in mass was found to be 1.5–3% and the strength loss was found to be 35%–45%. In the case of salt solution exposure, the loss in mass was seen to be 1–2% and whereas in the case of strength, the loss was found to be 30%–42%, respectively. Further, the sustainability aspects of the concrete with industrial effluents were examined in detail; focusing on economic value of the concrete, carbon emission and energy demand during the production of concrete.