Electrochemical C–H arylation of heteroarenes with in situ diazotizated anilines

IF 1.8 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Mendeleev Communications Pub Date : 2024-07-01 DOI:10.1016/j.mencom.2024.06.036

Zhen-Xiang Liu, Hui Mao, Hang-Cheng Ni, Tai-Jin Chen

引用次数: 0

Abstract

A simple and efficient electrochemical C–H arylation of five- membered active heteroarenes involves the application of arenediazonium salts generated in situ from anilines and tert- butyl nitrite. A cathodic reduction-induced radical chain mechanism is proposed.

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原位重氮化苯胺与杂环烯的电化学 C-H 芳基化反应

五元活性杂环戊烯的一种简单高效的 C-H 芳基化电化学方法涉及到苯胺和亚硝酸叔丁酯原位生成的戊二氮盐的应用。提出了一种阴极还原诱导的自由基链机制。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Mendeleev Communications 化学-化学综合

CiteScore

3.00

自引率

21.10%

发文量

226

审稿时长

4-8 weeks

期刊介绍： Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.