Enhancing the cryogenic performance of superconducting magnet encapsulation resins with hyperbranched polymers: A molecular dynamics simulation and experimental study

Abstract

Epoxy resin (EP) plays a crucial role in safeguarding superconducting magnets. One of the major concerns related to its usage is its inherent susceptibility to cracking under cryogenic temperatures and the strong electromagnetic forces experienced during the operation of superconducting magnets. In this study, we utilize molecular dynamics (MD)simulation and cryogenic experiments to conduct a comprehensive investigation aimed at gaining a profound understanding of the cryogenic toughening mechanism in hyperbranched polymers-toughened (HBPs) EPs. Five different crosslinking models of EP composites were established by MD simulations. The performance parameters obtained from the MD simulation calculations are highly consistent with the experimental results, which included the glass transition temperature, coefficient of thermal expansion, mechanical properties, free volume and atomic mean square displacement. Moreover, the relationship between structural changes and properties of the MD models was investigated. This research method provides a new avenue of exploration for superconducting magnet encapsulation resin materials.