Synergistic effect of iron-based metal-organic framework hybridized with carbon quantum dots in agar/gelatin films for fruit preservation

IF 8.5 1区 农林科学 Q1 FOOD SCIENCE & TECHNOLOGY
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引用次数: 0

Abstract

A novel hybrid nanostructure was synthesized by functionalizing an iron-based metal-organic framework (MOF) with carbon quantum dots (CD@MOF). The developed CD@MOF had an octahedral crystal structure and exhibited favorable antioxidant, antifungal, and antibacterial activities. MOF and CD@MOF particles are incorporated into agar/gelatin (Agar/Gel) blend polymers. The compatibility and dispersion of CD@MOF in the polymer were confirmed through FTIR, XPS, and SEM analysis. The conjugation of MOF with CDs enriched in active edges resulted in superb antioxidant (71.9 % DPPH and 100 % ABTS) and antibacterial activities. The addition of CD@MOF increased the tensile strength and gas (water vapor and oxygen) barrier and UV barrier (100 % UV blocking) properties of the film. In addition, tomato fruits were packaged with fabricated films and stored at 4 ℃ for 24 days, and quality changes were investigated. The experimental outcomes indicated the effective preservation performance of the Agar/Gel/CD@MOF films on packaged tomatoes.

用于水果保鲜的琼脂/明胶薄膜中铁基金属有机框架与碳量子点杂化的协同效应
通过将铁基金属有机框架(MOF)与碳量子点(CD@MOF)功能化,合成了一种新型混合纳米结构。所开发的 CD@MOF 具有八面体晶体结构,并表现出良好的抗氧化、抗真菌和抗菌活性。MOF 和 CD@MOF 颗粒被加入琼脂/明胶(Agar/Gel)共混聚合物中。傅立叶变换红外光谱、XPS 和扫描电镜分析证实了 CD@MOF 在聚合物中的相容性和分散性。MOF 与富含活性边的 CD 共轭后,产生了极好的抗氧化(71.9% DPPH 和 100%ABTS)和抗菌活性。CD@MOF 的加入提高了薄膜的拉伸强度、气体(水蒸气和氧气)阻隔性和紫外线阻隔性(100% 紫外线阻隔)。此外,用制作好的薄膜包装番茄果实,在 4 ℃ 下保存 24 天,并调查其质量变化。实验结果表明,琼脂/凝胶/CD@MOF 薄膜对包装番茄具有有效的保鲜性能。
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来源期刊
Food Packaging and Shelf Life
Food Packaging and Shelf Life Agricultural and Biological Sciences-Food Science
CiteScore
14.00
自引率
8.80%
发文量
214
审稿时长
70 days
期刊介绍: Food packaging is crucial for preserving food integrity throughout the distribution chain. It safeguards against contamination by physical, chemical, and biological agents, ensuring the safety and quality of processed foods. The evolution of novel food packaging, including modified atmosphere and active packaging, has extended shelf life, enhancing convenience for consumers. Shelf life, the duration a perishable item remains suitable for sale, use, or consumption, is intricately linked with food packaging, emphasizing its role in maintaining product quality and safety.
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