Synthesis of the aureus nano-silica utilizing acid orange 7 for strengthening and coloring fluororubber

IF 2.6 4区 化学 Q3 POLYMER SCIENCE
Zhangyan Qiu, Junchang Gao, Yadong Wu, Lingfeng Wang, Zhukang Bai, Yili Wei, Ping Shen, Yiwen Zhang, Wenjie Tan, Huile Jin
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引用次数: 0

Abstract

Fluororubber (FKM) has an important application in the industrial field. However, the coloring problem of FKM has been affecting the performance of its mechanical properties. Herein, a novel silicon dioxide (SiO2) colored with acid orange 7 (AO7) was prepared by sol–gel method to ameliorate the mechanical properties and coloring property of FKM. Acid orange silica sol was prepared by adding AO7 to sodium silicate solution, and then colored SiO2-AO7 was prepared by freeze drying. The effects of SiO2-AO7 modified FKM on mechanical properties, thermal conductivity and coloring were systematically studied. The results show that SiO2-AO7 has the advantage of enhancing the mechanical properties of FKM without affecting its color appearance. Relative to the unmodified FKM, the tensile strength and modulus at 300% elongation saw enhancements of 47.2% and 21.8% respectively. The SiO2-AO7 offers exceptional coloration and mechanical reinforcement, showing strong suitability for industrial application.

Abstract Image

利用酸性橙 7 合成金黄色纳米二氧化硅,用于氟橡胶的强化和着色
氟橡胶(FKM)在工业领域有着重要的应用。然而,FKM 的着色问题一直影响着其机械性能的发挥。本文采用溶胶-凝胶法制备了一种用酸性橙 7(AO7)着色的新型二氧化硅(SiO2),以改善 FKM 的机械性能和着色性能。将酸性橙 7 加入硅酸钠溶液中制备酸性橙二氧化硅溶胶,然后通过冷冻干燥制备有色 SiO2-AO7。系统研究了 SiO2-AO7 改性 FKM 对力学性能、热导率和着色的影响。结果表明,SiO2-AO7 具有增强 FKM 力学性能的优点,同时不影响其颜色外观。与未改性的 FKM 相比,拉伸强度和 300% 延伸率下的模量分别提高了 47.2% 和 21.8%。SiO2-AO7 具有优异的着色和机械增强性能,非常适合工业应用。
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来源期刊
Journal of Polymer Research
Journal of Polymer Research 化学-高分子科学
CiteScore
4.70
自引率
7.10%
发文量
472
审稿时长
3.6 months
期刊介绍: Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology. As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including: polymer synthesis; polymer reactions; polymerization kinetics; polymer physics; morphology; structure-property relationships; polymer analysis and characterization; physical and mechanical properties; electrical and optical properties; polymer processing and rheology; application of polymers; supramolecular science of polymers; polymer composites.
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