Determination and interpretation of firing temperature in ancient porcelain utilizing thermal expansion analysis

Abstract

This study utilizes a multidisciplinary approach, combining simulation experiments, thermal expansion analysis, XRD, SEM, and physical property assessments to investigate the firing temperature in illitic-kaolinitic porcelain. Our findings indicate that the accuracy of the thermal expansion method depends on both the actual firing temperature and dwell time. When dwell time is uncertain, the method provides a range of possible actual firing temperatures, differing by approximately 100 °C. Remarkably, as the porcelain body nears full vitrification, the determined firing temperature tends to be notably higher. A critical analysis of previous research suggests potential overestimation of ancient kiln temperatures. Additionally, our study highlights the usefulness of bulk density, water absorption, porosity, and mullite content in determining dwell time. Overall, our research offers new insights into ancient porcelain firing processes.