Growth and ferroelectric properties of SrBi2Ta2O9 thin films on highly oriented pyrolytic graphite substrates with atomic structure like graphene surface

IF 3.5 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Eunmi Lee, Jong Yeog Son
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Abstract

Layered perovskite-structured thin films of SrBi2Ta2O9 (SBT) were successfully deposited onto highly oriented pyrolytic graphite substrates using a pulse laser deposition technique, resulting in an atomic structure identical to that of the graphene surface. The SBT thin films exhibited enhanced ferroelectric and dielectric properties when the substrate temperature was slightly lowered, attributed to the improvement in a-oriented crystallinity. Due to the enhancement in a-oriented crystallinity, the SBT thin films exhibited an improved remanent polarization of approximately 12.3 μC/cm2 and an enhanced remanent piezoelectric coefficient of approximately 13.6 pm/V. The observations of ferroelectric domain structures using piezoresponse force microscopy confirmed a slight increase in domain boundary energy for SBT thin films with enhanced a-oriented crystallinity.

Graphical abstract

Abstract Image

在具有类似石墨烯表面原子结构的高取向热解石墨基底上生长的 SrBi2Ta2O9 薄膜及其铁电特性
利用脉冲激光沉积技术,成功地在高取向热解石墨基底上沉积了层状透辉石结构的 SrBi2Ta2O9(SBT)薄膜,从而获得了与石墨烯表面相同的原子结构。当基底温度略微降低时,SBT 薄膜的铁电性和介电性都有所增强,这归功于 a 向结晶度的提高。由于 a 向结晶度的提高,SBT 薄膜的剩磁极化得到改善,约为 12.3 μC/cm2,剩磁压电系数提高,约为 13.6 pm/V。使用压电响应力显微镜观察铁电畴极结构证实,面向结晶性增强的 SBT 薄膜的畴极边界能量略有增加。
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来源期刊
Journal of Materials Science
Journal of Materials Science 工程技术-材料科学:综合
CiteScore
7.90
自引率
4.40%
发文量
1297
审稿时长
2.4 months
期刊介绍: The Journal of Materials Science publishes reviews, full-length papers, and short Communications recording original research results on, or techniques for studying the relationship between structure, properties, and uses of materials. The subjects are seen from international and interdisciplinary perspectives covering areas including metals, ceramics, glasses, polymers, electrical materials, composite materials, fibers, nanostructured materials, nanocomposites, and biological and biomedical materials. The Journal of Materials Science is now firmly established as the leading source of primary communication for scientists investigating the structure and properties of all engineering materials.
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