{"title":"The effects of medium and friction pair on the tribological behavior of Mo-doped DLC films","authors":"","doi":"10.1016/j.diamond.2024.111464","DOIUrl":null,"url":null,"abstract":"<div><p>Diamond-like carbon (DLC) films are widely used to improve the tribological properties of key components in internal combustion engines. However, their performance can be significantly affected by the service environment, which may impact engine reliability. This study investigates the impact of various media and friction pairs on the tribological behavior of molybdenum-doped DLC (Mo-DLC) films. The results demonstrate that Mo-DLC films exhibit excellent tribological properties across different media, showcasing their adaptability to various conditions. The lubrication mechanism varies with media viscosity: in methanol, Mo-DLC films operate under boundary lubrication conditions, leading to a relatively high wear rate of approximately 5.2 × 10<sup>−8</sup> mm<sup>3</sup>/N·m. Conversely, in diesel and polyalphaolefin-based oil (PAO), where fluid dynamic lubrication occurs, wear rates are significantly lower, at 4.4 × 10<sup>−8</sup> mm<sup>3</sup>/N·m and 3.1 × 10<sup>−8</sup> mm<sup>3</sup>/N·m, respectively. In addition, the friction pair significantly influences the tribological performance of the Mo-DLC film. When paired with D-GCr15 in methanol, Mo-DLC films exhibit a low friction coefficient of 0.09 and a wear rate of 1.6 × 10<sup>−8</sup> mm<sup>3</sup>/N·m, respectively. However, when coupled with N-GCr15, the increased surface roughness extends the running-in period and raises the friction coefficient in methanol. These findings offer valuable theoretical insights and practical guidance for optimizing DLC films in internal combustion engines.</p></div>","PeriodicalId":11266,"journal":{"name":"Diamond and Related Materials","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Diamond and Related Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925963524006770","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
引用次数: 0
Abstract
Diamond-like carbon (DLC) films are widely used to improve the tribological properties of key components in internal combustion engines. However, their performance can be significantly affected by the service environment, which may impact engine reliability. This study investigates the impact of various media and friction pairs on the tribological behavior of molybdenum-doped DLC (Mo-DLC) films. The results demonstrate that Mo-DLC films exhibit excellent tribological properties across different media, showcasing their adaptability to various conditions. The lubrication mechanism varies with media viscosity: in methanol, Mo-DLC films operate under boundary lubrication conditions, leading to a relatively high wear rate of approximately 5.2 × 10−8 mm3/N·m. Conversely, in diesel and polyalphaolefin-based oil (PAO), where fluid dynamic lubrication occurs, wear rates are significantly lower, at 4.4 × 10−8 mm3/N·m and 3.1 × 10−8 mm3/N·m, respectively. In addition, the friction pair significantly influences the tribological performance of the Mo-DLC film. When paired with D-GCr15 in methanol, Mo-DLC films exhibit a low friction coefficient of 0.09 and a wear rate of 1.6 × 10−8 mm3/N·m, respectively. However, when coupled with N-GCr15, the increased surface roughness extends the running-in period and raises the friction coefficient in methanol. These findings offer valuable theoretical insights and practical guidance for optimizing DLC films in internal combustion engines.
期刊介绍:
DRM is a leading international journal that publishes new fundamental and applied research on all forms of diamond, the integration of diamond with other advanced materials and development of technologies exploiting diamond. The synthesis, characterization and processing of single crystal diamond, polycrystalline films, nanodiamond powders and heterostructures with other advanced materials are encouraged topics for technical and review articles. In addition to diamond, the journal publishes manuscripts on the synthesis, characterization and application of other related materials including diamond-like carbons, carbon nanotubes, graphene, and boron and carbon nitrides. Articles are sought on the chemical functionalization of diamond and related materials as well as their use in electrochemistry, energy storage and conversion, chemical and biological sensing, imaging, thermal management, photonic and quantum applications, electron emission and electronic devices.
The International Conference on Diamond and Carbon Materials has evolved into the largest and most well attended forum in the field of diamond, providing a forum to showcase the latest results in the science and technology of diamond and other carbon materials such as carbon nanotubes, graphene, and diamond-like carbon. Run annually in association with Diamond and Related Materials the conference provides junior and established researchers the opportunity to exchange the latest results ranging from fundamental physical and chemical concepts to applied research focusing on the next generation carbon-based devices.