Research on the Corrosion Inhibition Effect of Xanthium sibiricum on Reinforced Steel and the Prediction of Reinforced Concrete Performance under a Stray Current and Chloride Environment

Qi Liu, Min Yuan, Jiaming Zhang, Sheng Qiang
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Abstract

This study examined a newly developed environmentally friendly plant-based corrosion inhibitor (Xanthium sibiricum). The natural potential method, linear polarization method, steel weight loss method, and corrosion area method were employed to verify the inhibitor’s effectiveness in chloride-containing concrete. The results indicated that Xanthium sibiricum elevated the natural potential of reinforcing steel in concrete, increased its self-corrosion potential, and reduced the self-corrosion current. After three months of curing, the corrosion rate of steel without an inhibitor was approximately 47.5% faster than the experimental group, with the steel loss rate about 40% more severe. The effectiveness of the inhibitor was influenced by increased chloride content in concrete. A two-dimensional multiphase ion transport model of reinforced concrete with realistic aggregate distribution was established using the finite element method (FEM). This model simulated chloride ion transport under typical civil engineering service environments—the coupled effects of a stray current and chloride environment. A predictive formula for the residual compressive strength of reinforced concrete was derived after corrosion under various voltages and chloride ion concentrations for a specific duration. In conjunction with a pump station project operating in a similar environment, the optimal dosage of the Xanthium sibiricum inhibitor for practical engineering was determined to be 2 g/L. At this dosage, the strength of reinforced concrete specimens increased by approximately 31.1%. Finally, a predictive formula for the residual compressive strength of reinforced concrete with an added inhibitor was obtained after corrosion under various voltages and chloride ion concentrations for a specific duration. The conclusions can enhance the durability and safety of concrete structures in similar projects, showing promising application prospects.
杂散电流和氯化物环境下西伯利亚黄刺玫对钢筋的缓蚀作用及钢筋混凝土性能预测研究
本研究考察了一种新开发的环境友好型植物缓蚀剂(西伯利亚黄刺玫)。采用自然电位法、线性极化法、钢材失重法和腐蚀面积法验证了该缓蚀剂在含氯混凝土中的有效性。结果表明,西红花提高了混凝土中钢筋的自然电位,增加了其自腐蚀电位,降低了自腐蚀电流。养护三个月后,未使用抑制剂的钢筋腐蚀速度比实验组快约 47.5%,钢筋损失率严重约 40%。抑制剂的效果受混凝土中氯化物含量增加的影响。利用有限元法(FEM)建立了一个具有真实骨料分布的钢筋混凝土二维多相离子传输模型。该模型模拟了典型土木工程服务环境下的氯离子迁移--杂散电流和氯离子环境的耦合效应。得出了钢筋混凝土在不同电压和氯离子浓度下腐蚀一定时间后的残余抗压强度预测公式。结合在类似环境中运行的泵站项目,确定了实际工程中西伯利亚黄刺玫抑制剂的最佳用量为 2 克/升。在此剂量下,钢筋混凝土试样的强度提高了约 31.1%。最后,还得出了添加了抑制剂的钢筋混凝土在不同电压和氯离子浓度下腐蚀一定时间后的残余抗压强度预测公式。这些结论可以提高类似工程中混凝土结构的耐久性和安全性,具有广阔的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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