María Alonso-González, Manuel Felix, Alberto Romero, Claudia Sergi, Irene Bavasso, Fabrizio Sarasini
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引用次数: 0
Abstract
Conventional plastics pose environmental threats due to their non-biodegradable nature and their reliability on fossil resources, leading to the exploration of sustainable alternatives. In this sense, biodegradable bioplastics derived from renewable resources offer a promising solution to mitigate ecological impacts. This study focuses on the combination of extrusion and injection molding for the development of rice bran-based bioplastics. Being a by-product from the rice industry rich in starches and proteins, rice bran is an abundant and non-expensive resource that contributes to an enhanced waste management and represents a step forward in integrating the principles of a circular economy. This study delves into the optimization of processing conditions through a Design of Experiment approach. For this purpose, the number of extrusion steps, cylinder and mold temperatures, and injection pressure were investigated. The results showed that two extrusion steps led to a significant increase of approximately 22.8% in Young’s modulus and 37.5% in tensile strength compared to a single extrusion cycle. This enhancement was attributed to the facilitation of starch gelatinization and biopolymer-plasticizer interactions (achieving thermoplastic starch and protein plasticization). Similarly, manipulation of injection temperatures and pressure had notable effects on tensile properties, highlighting the complex interplay between processing parameters. In particular, when using cylinder and mold temperatures of 110 °C and 180 °C, respectively, along with 800 bar, it was possible to achieve a further enhancement in tensile properties, with an increase of 97.1% in Young’s modulus and over 100% in tensile strength. Overall, this research underscores the importance of understanding the relationship between processing conditions and biopolymer interactions for bioplastic production.
期刊介绍:
The Journal of Polymers and the Environment fills the need for an international forum in this diverse and rapidly expanding field. The journal serves a crucial role for the publication of information from a wide range of disciplines and is a central outlet for the publication of high-quality peer-reviewed original papers, review articles and short communications. The journal is intentionally interdisciplinary in regard to contributions and covers the following subjects - polymers, environmentally degradable polymers, and degradation pathways: biological, photochemical, oxidative and hydrolytic; new environmental materials: derived by chemical and biosynthetic routes; environmental blends and composites; developments in processing and reactive processing of environmental polymers; characterization of environmental materials: mechanical, physical, thermal, rheological, morphological, and others; recyclable polymers and plastics recycling environmental testing: in-laboratory simulations, outdoor exposures, and standardization of methodologies; environmental fate: end products and intermediates of biodegradation; microbiology and enzymology of polymer biodegradation; solid-waste management and public legislation specific to environmental polymers; and other related topics.