High-performance asymmetric supercapacitor electrode materials NiCo2S4@NiCo-LDH@Ni foam

IF 2.4 4区 化学 Q3 CHEMISTRY, PHYSICAL
Ionics Pub Date : 2024-08-01 DOI:10.1007/s11581-024-05739-3
Yan Gu, Bingyan Du, Yifan Bai, Lu Yang, Yunpeng Wang, XuanLin Li, XiaoShan Liu
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引用次数: 0

Abstract

Composite electrode materials often have excellent electrochemical properties; however, their preparation often requires multiple steps. Therefore, to further reduce the time and preparation cost, a NiCo2S4@NiCo-layered double hydroxide (NiCo-LDH) composite electrode material was prepared by a one-step method in this study. In the three-electrode system, the specific capacitance was 7462.5 mF cm−2 at a current density of 5 mA cm−2. Moreover, the specific capacitance was maintained at 78.4% after 6000 cycles. To further verify its practical application, we assembled an asymmetric supercapacitor using activated carbon as the anode material and NiCo2S4@NiCo-LDH as the positive material. The results show that the capacity of the device can still be maintained at 80% of its original capacity after 5000 cycles. This shows that the NiCo2S4@NiCo-LDH@NF electrode material has good application prospects.

Abstract Image

高性能不对称超级电容器电极材料 NiCo2S4@NiCo-LDH@Ni 泡沫
复合电极材料通常具有优异的电化学性能,但其制备通常需要多个步骤。因此,为了进一步缩短时间和降低制备成本,本研究采用一步法制备了 NiCo2S4@NiCo 层状双氢氧化物(NiCo-LDH)复合电极材料。在三电极系统中,当电流密度为 5 mA cm-2 时,比电容为 7462.5 mF cm-2。此外,在 6000 次循环后,比电容保持在 78.4%。为了进一步验证其实际应用,我们以活性炭为阳极材料,NiCo2S4@NiCo-LDH 为正极材料,组装了一个不对称超级电容器。结果表明,该装置的容量在循环 5000 次后仍能保持在原始容量的 80%。这表明 NiCo2S4@NiCo-LDH@NF 电极材料具有良好的应用前景。
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来源期刊
Ionics
Ionics 化学-电化学
CiteScore
5.30
自引率
7.10%
发文量
427
审稿时长
2.2 months
期刊介绍: Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.
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