Thermal analysis of various chromium compounds using TGA and DSC methods: a comparative investigation

IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL
Seyed Ali Akbar Sajadi, Zeynab Khorablou, Alireza Nazari Alavi
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引用次数: 0

Abstract

This study explored thermal behavior of four kinds of chromium compounds such as CrO3, K2Cr2O7, K2CrO4, and Cr2O3 using thermogravimetry (TG) and differential scanning calorimetry (DSC) method under the oxygen (O2) and nitrogen (N2) gas atmosphere at varying temperatures (25 to 1600 ℃). A diverse of chromium compounds were carefully evaluated for the first time through this method, and the present work provides new, comprehensive and valuable information regarding the mentioned compounds. XRD technique and elemental analysis were applied in order to recognize the products at diverse decomposition stages. The obtained products were then investigated via a SEM electron microscope. Also, the form and the size of crystals were explored. Interestingly, the results obtained from both TG and DSC experiments in O2 and N2 atmospheres were identical. The thermodynamic data obtained from DSC experiments are reported in this work. Along with ∆H for each peak. It was shown that the decomposition product of K2Cr2O7 was also a mixture of Cr2O3 and K2CrO4 at 1400 °C.

This study explored thermal behavior of four kinds of chromium compounds such as CrO3, K2Cr2O7, K2CrO4, and Cr2O3 using thermogravimetry (TG) and differential scanning calorimetry (DSC) method under the oxygen (O2) and nitrogen (N2) gas atmosphere at varying temperatures (25 to 1600 ℃). A diverse of chromium compounds were carefully evaluated for the first time through this method, and the present work provides new, comprehensive and valuable information regarding the mentioned compounds. XRD technique and elemental analysis were applied in order to recognize the products at diverse decomposition stages. The obtained products were then investigated via a SEM electron microscope. Also, the form and the size of crystals were explored. Interestingly, the results obtained from both TG and DSC experiments in O2 and N2 atmospheres were identical. The thermodynamic data obtained from DSC experiments are reported in this work. Along with ∆H for each peak. It was shown that the decomposition product of K2Cr2O7 was also a mixture of Cr2O3 and K2CrO4 at 1400 °C.

Abstract Image

Abstract Image

使用 TGA 和 DSC 方法对各种铬化合物进行热分析:对比研究
本研究采用热重法(TG)和差示扫描量热法(DSC),在不同温度(25 至 1600 ℃)的氧气(O2)和氮气(N2)气氛下,探讨了 CrO3、K2Cr2O7、K2CrO4 和 Cr2O3 等四种铬化合物的热行为。本研究首次采用这种方法对多种铬化合物进行了仔细评估,为上述化合物提供了新的、全面和有价值的信息。为了识别不同分解阶段的产物,我们应用了 XRD 技术和元素分析。然后通过 SEM 电子显微镜对获得的产物进行了研究。此外,还对晶体的形态和大小进行了研究。有趣的是,在 O2 和 N2 大气中进行的 TG 和 DSC 实验得到的结果完全相同。本文报告了通过 DSC 实验获得的热力学数据。以及每个峰的∆H。本研究采用热重法(TG)和差示扫描量热法(DSC),在氧气(O2)和氮气(N2)气氛下,在不同温度(25 至 1600 ℃)下探讨了 CrO3、K2Cr2O7、K2CrO4 和 Cr2O3 等四种铬化合物的热行为。本研究首次采用这种方法对多种铬化合物进行了仔细评估,为上述化合物提供了新的、全面和有价值的信息。为了识别不同分解阶段的产物,我们应用了 XRD 技术和元素分析。然后通过 SEM 电子显微镜对获得的产物进行了研究。此外,还对晶体的形态和大小进行了研究。有趣的是,在 O2 和 N2 大气中进行的 TG 和 DSC 实验得到的结果完全相同。本文报告了通过 DSC 实验获得的热力学数据。以及每个峰的∆H。结果表明,在 1400 ℃ 时,K2Cr2O7 的分解产物也是 Cr2O3 和 K2CrO4 的混合物。
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来源期刊
CiteScore
8.50
自引率
9.10%
发文量
577
审稿时长
3.8 months
期刊介绍: Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews. The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.
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