Synthesis of locust bean gum/titanium dioxide hydrogel nanocomposites for efficient removal of methylene blue from aqueous solution

IF 4.7 3区 工程技术 Q2 ENGINEERING, ENVIRONMENTAL
Boitumelo Rejoice Motshabi, Edwin Makhado, Nompumelelo Malatji, Kwena Desmond Modibane, Mpitloane Joseph Hato, Orebotse Joseph Botlhoko, Mahmoud H. Abu Elella
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Abstract

In this study, we are interested in preparing novel hydrogel and hydrogel nanocomposite-based adsorbents for removing methylene blue (MB) dye based on grafted locust bean gum (LBG). LBG hydrogel and hydrogel nanocomposite were synthesized using a radical polymerization technique in the absence and presence of TiO2 with LBG-cl-(acrylic acid (AA)-co-acrylamide (AAm)). Various analytical instruments Fourier transform infrared (FTIR), X-Ray diffraction (XRD), Scanning electron microscopy (SEM), and High-resolution transmission electron microscopy (HRTEM) were used to elucidate the chemical structure and surface morphology of the prepared samples. Using a batch adsorption experiment, the Langmuir isotherm model showed that LBG-cl-p(AA-co-AAm) hydrogel had a maximum adsorption capacity of 1540.9 mg/g and LBG-cl-(AA-co-AAm)/TiO2 hydrogel nanocomposites had a maximum adsorption capacity of 1273.4 mg/g at neutral pH. The thermodynamic data demonstrated that MB dye was removed via spontaneous adsorption. Furthermore, the regeneration study showed good recyclability for the obtained hydrogel nanocomposites through six consecutive reusable cycles. Therefore, the hydrogel nanocomposites are an effective adsorbent for the removal of MB dye from aqueous solutions.

Abstract Image

合成用于从水溶液中高效去除亚甲基蓝的槐豆胶/二氧化钛水凝胶纳米复合材料
在本研究中,我们致力于制备基于接枝槐豆胶(LBG)的新型水凝胶和水凝胶纳米复合材料吸附剂,用于去除亚甲基蓝(MB)染料。在没有 TiO2 和有 TiO2 的情况下,采用自由基聚合技术合成了 LBG 水凝胶和水凝胶纳米复合材料,LBG-cl-(丙烯酸(AA)-共丙烯酰胺(AAm))。利用傅立叶变换红外(FTIR)、X 射线衍射(XRD)、扫描电子显微镜(SEM)和高分辨率透射电子显微镜(HRTEM)等分析仪器来阐明所制备样品的化学结构和表面形态。通过批量吸附实验,Langmuir 等温线模型表明,在中性 pH 条件下,LBG-cl-p(AA-co-AAm)水凝胶的最大吸附容量为 1540.9 mg/g,LBG-cl-(AA-co-AAm)/TiO2 水凝胶纳米复合材料的最大吸附容量为 1273.4 mg/g。热力学数据表明,甲基溴染料是通过自发吸附去除的。此外,再生研究表明,所获得的水凝胶纳米复合材料具有良好的可回收性,可连续重复使用六次。因此,水凝胶纳米复合材料是去除水溶液中甲基溴染料的有效吸附剂。
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来源期刊
Journal of Polymers and the Environment
Journal of Polymers and the Environment 工程技术-高分子科学
CiteScore
9.50
自引率
7.50%
发文量
297
审稿时长
9 months
期刊介绍: The Journal of Polymers and the Environment fills the need for an international forum in this diverse and rapidly expanding field. The journal serves a crucial role for the publication of information from a wide range of disciplines and is a central outlet for the publication of high-quality peer-reviewed original papers, review articles and short communications. The journal is intentionally interdisciplinary in regard to contributions and covers the following subjects - polymers, environmentally degradable polymers, and degradation pathways: biological, photochemical, oxidative and hydrolytic; new environmental materials: derived by chemical and biosynthetic routes; environmental blends and composites; developments in processing and reactive processing of environmental polymers; characterization of environmental materials: mechanical, physical, thermal, rheological, morphological, and others; recyclable polymers and plastics recycling environmental testing: in-laboratory simulations, outdoor exposures, and standardization of methodologies; environmental fate: end products and intermediates of biodegradation; microbiology and enzymology of polymer biodegradation; solid-waste management and public legislation specific to environmental polymers; and other related topics.
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