In situ Synthesis of Nano-CeO2 Composite with Chitosan

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
L. A. Zemskova, V. E. Silant’ev, D. Kh. Shlyk
{"title":"In situ Synthesis of Nano-CeO2 Composite with Chitosan","authors":"L. A. Zemskova, V. E. Silant’ev, D. Kh. Shlyk","doi":"10.1134/s0036023624600515","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Nanosized cerium oxide (CeO<sub>2</sub>) particles were prepared by co-precipitation using chitosan as a template, cerium(III) nitrate and cerium(IV) sulfate as starting substances, and aqueous ammonia as a precipitating agent. According to powder X-ray diffraction data, cerianite with face-centered cubic phase is formed in the reaction systems. The size of the coherent scattering regions is not more than ⁓3 nm. Fourier transform IR spectroscopy data indicate to interaction of polymer molecules with the inorganic component. The shift of N–H absorption bands for composites containing Ce(III) and Ce(IV) compared to those of chitosan indicates that amino groups interact with CeO<sub>2</sub> particles loaded in the polymer. The use of chitosan as a matrix for the synthesis of CeO<sub>2</sub> nanoparticles showed that this approach is more economical and facile to produce nanomaterials for various applications.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"41 1","pages":""},"PeriodicalIF":1.8000,"publicationDate":"2024-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s0036023624600515","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

Abstract

Nanosized cerium oxide (CeO2) particles were prepared by co-precipitation using chitosan as a template, cerium(III) nitrate and cerium(IV) sulfate as starting substances, and aqueous ammonia as a precipitating agent. According to powder X-ray diffraction data, cerianite with face-centered cubic phase is formed in the reaction systems. The size of the coherent scattering regions is not more than ⁓3 nm. Fourier transform IR spectroscopy data indicate to interaction of polymer molecules with the inorganic component. The shift of N–H absorption bands for composites containing Ce(III) and Ce(IV) compared to those of chitosan indicates that amino groups interact with CeO2 particles loaded in the polymer. The use of chitosan as a matrix for the synthesis of CeO2 nanoparticles showed that this approach is more economical and facile to produce nanomaterials for various applications.

Abstract Image

与壳聚糖原位合成纳米二氧化钴复合材料
摘要 以壳聚糖为模板,硝酸铈(III)和硫酸铈(IV)为起始物质,氨水为沉淀剂,采用共沉淀法制备了纳米氧化铈(CeO2)颗粒。根据粉末 X 射线衍射数据,反应体系中形成了面心立方相的铈镧矿。相干散射区的大小不超过 ⁓3 nm。傅立叶变换红外光谱数据表明聚合物分子与无机成分发生了相互作用。与壳聚糖相比,含有 Ce(III) 和 Ce(IV) 的复合材料的 N-H 吸收带发生了移动,这表明氨基与聚合物中的 CeO2 颗粒发生了相互作用。使用壳聚糖作为合成 CeO2 纳米粒子的基质表明,这种方法更经济、更容易生产出用于各种应用的纳米材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信