D. Farrimond, S. Woolford, A. D. Barr, T. Lodge, A. Tyas, R. Waddoups, S. D. Clarke, S. E. Rigby, M. J. Hobbs, J. R. Willmott, M. Whittaker, D. J. Pope, M. Handy
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引用次数: 0
Abstract
When explosives detonate in a confined space, repeated boundary reflections result in complex shock interactions and the formation of a uniform quasi-static pressure (QSP). For fuel-rich explosives, mixing of partially oxidized detonation products with an oxygen-rich atmosphere results in a further energy release through rapid secondary combustion or ‘afterburn’. While empirical formulae and thermochemical modelling approaches have been developed to predict QSP, a lack of high-fidelity experimental data means questions remain around the deterministic quality of confined explosions, and the magnitude and mechanisms of afterburn reactions. This article presents experimental data for RDX- and PETN-based plastic explosives, demonstrating the high repeatability of the QSP generated in a sealed chamber using pressure transducers and high-speed infrared thermometry. Detonations in air, nitrogen and argon atmospheres are used to identify the contribution of afterburn to total QSP, to estimate the duration of afterburn reactions and to speculate on the flame temperature associated with this mechanism. Computational fluid dynamic modelling of the experiments was also able to accurately predict these effects. Understanding and quantifying explosions in complex environments are critical for the design of effective protective structures: the mechanisms described here provide a significant step towards the development of fast-running engineering models for internal blast events.
期刊介绍:
ACS Applied Bio Materials is an interdisciplinary journal publishing original research covering all aspects of biomaterials and biointerfaces including and beyond the traditional biosensing, biomedical and therapeutic applications.
The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important bio applications. The journal is specifically interested in work that addresses the relationship between structure and function and assesses the stability and degradation of materials under relevant environmental and biological conditions.