Effective separation of coal gasification fine slag: Role of classification and ultrasonication in enhancing flotation

IF 11.7 1区 工程技术 Q1 MINING & MINERAL PROCESSING
Rui Han , Anning Zhou , Ningning Zhang , Zhen Li , Mengyan Cheng , Xiaoyi Chen , Tianhao Nan
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Abstract

Effective separation of residual carbon and ash is the basis for the resource utilization of coal gasification fine slag (CGFS). The conventional flotation process of CGFS has the bottlenecks of low carbon recovery and high collector dosage. In order to address these issues, CGFS sample taken from Shaanxi, China was used as the study object in this paper. A new process of size classification − fine grain ultrasonic pretreatment flotation (SC-FGUF) was proposed and its separation effect was compared with that of whole-grain flotation (WGF) as well as size classification − fine grain flotation (SC-FGF). The mechanism of its enhanced separation effect was revealed through flotation kinetic fitting, flotation flow foam layer stability, particle size composition, surface morphology, pore structure, and surface chemical property analysis. The results showed that compared with WGF, pre-classification could reduce the collector dosage by 84.09% and the combination of pre-classification and ultrasonic pretreatment could increase the combustible recovery by 17.29% and up to 93.46%. The SC-FGUF process allows the ineffective adsorption of coarse residual carbon to collector during flotation stage to be reduced by pre-classification, and the tightly embedded state of fine CGFS particles is disrupted and surface oxidizing functional group occupancy was reduced by ultrasonic pretreatment, thus carbon and ash is easier to be separated in the flotation process. In addition, some of the residual carbon particles were broken down to smaller sizes in the ultrasonic pretreatment, which led to an increase in the stability of flotation flow foam layer and a decrease in the probability of detachment of residual carbon particles from the bubbles. Therefore, SC-FGUF could increase the residual carbon recovery and reduce the flotation collector dosage, which is an innovative method for carbon-ash separation of CGFS with good application prospect.

煤气化细渣的有效分离:分级和超声波在提高浮选效果中的作用
有效分离残炭和灰渣是煤气化细渣(CGFS)资源化利用的基础。传统的煤气化细渣浮选工艺存在碳回收率低、捕收剂用量大等瓶颈问题。针对这些问题,本文以中国陕西的煤气化细渣样品为研究对象。提出了粒度分级-细粒超声波预处理浮选(SC-FGUF)新工艺,并比较了其与全粒浮选(WGF)和粒度分级-细粒浮选(SC-FGF)的分离效果。通过浮选动力学拟合、浮选流动泡沫层稳定性、粒度组成、表面形态、孔隙结构和表面化学性质分析,揭示了其提高分离效果的机理。结果表明,与 WGF 相比,预分级可减少 84.09% 的捕收剂用量,预分级与超声波预处理相结合可提高 17.29% 的可燃物回收率,最高可达 93.46%。SC-FGUF工艺通过预分级减少了粗残炭在浮选阶段对捕收剂的无效吸附,通过超声波预处理破坏了CGFS细颗粒的紧密嵌布状态,减少了表面氧化官能团的占位,从而使碳灰在浮选过程中更容易分离。此外,部分残炭颗粒在超声波预处理中被分解成更小的尺寸,这导致浮选流动泡沫层的稳定性增加,残炭颗粒从气泡中脱离的概率降低。因此,SC-FGUF 可以提高残炭回收率,减少浮选捕收剂用量,是 CGFS 碳灰分离的一种创新方法,具有良好的应用前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
International Journal of Mining Science and Technology
International Journal of Mining Science and Technology Earth and Planetary Sciences-Geotechnical Engineering and Engineering Geology
CiteScore
19.10
自引率
11.90%
发文量
2541
审稿时长
44 days
期刊介绍: The International Journal of Mining Science and Technology, founded in 1990 as the Journal of China University of Mining and Technology, is a monthly English-language journal. It publishes original research papers and high-quality reviews that explore the latest advancements in theories, methodologies, and applications within the realm of mining sciences and technologies. The journal serves as an international exchange forum for readers and authors worldwide involved in mining sciences and technologies. All papers undergo a peer-review process and meticulous editing by specialists and authorities, with the entire submission-to-publication process conducted electronically.
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