Synthesis, structure and photoluminescent properties of far-red Y3Ga5O12:Cr3+ phosphors

Q2 Engineering
Sunyuezi Chen , Ziwei Lu , Yongfu Liu , Ruiyang Li , Peng Sun , Zhaohua Luo , Jun Jiang
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引用次数: 0

Abstract

Far-red (FR) photosensitive pigment (PFR) is vital for plant photomorphogenesis. Phosphor-converted (pc) LEDs are the next-generation FR light devices. How to obtain FR-emitting phosphors with a good quantum efficiency, suitable photoluminescence and high thermal stability is still difficult. Herein, we optimize the Y3Ga5O12:Cr3+ FR phosphor, which has an emission peak at 711 nm and a full width at half maximum of 74 nm, closing to the PFR absorption band. By adopting the solid-state sintering technology, the internal quantum efficiency reaches 85.5 %, more than 1.5 times higher than that reported by the liquid reaction (55 %). Furthermore, the external quantum efficiency reaches as high as 33.1 %, indicating the promising application in FR-LEDs.

远红外 Y3Ga5O12:Cr3+ 荧光粉的合成、结构和光致发光特性
远红(FR)光敏色素(PFR)对植物的光形态发生至关重要。荧光粉转换(pc)发光二极管是下一代远红外光设备。如何获得具有良好量子效率、合适光致发光和高热稳定性的红外发光荧光粉仍然是一个难题。在此,我们优化了 Y3Ga5O12:Cr3+ FR 荧光粉,其发射峰值为 711 nm,半最大全宽为 74 nm,接近 PFR 吸收带。通过采用固态烧结技术,内量子效率达到 85.5%,是液态反应(55%)的 1.5 倍以上。此外,外部量子效率高达 33.1%,表明其在 FR-LED 中的应用前景广阔。
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来源期刊
Optical Materials: X
Optical Materials: X Engineering-Electrical and Electronic Engineering
CiteScore
3.30
自引率
0.00%
发文量
73
审稿时长
91 days
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