{"title":"Unraveling the oxygen evolution activity of biomass-derived porous carbon plate as self-supported metal-free electrocatalyst for water splitting","authors":"","doi":"10.1016/j.pnsc.2024.07.007","DOIUrl":null,"url":null,"abstract":"<div><div><span>Developing the efficient and low-cost electrocatalysts<span><span> derived from biomass is a desired solution to address economy and sustainability challenges of hydrogen production<span> from water electrolysis due to utilizing metal-based catalysts. Herein, the peeled cornstalk-derived porous carbon<span><span> plates synthesized by salt template-assisted high-temperature pyrolysis are utilized as self-supported metal-free </span>electrocatalysts to unravel the oxygen evolution activity for alkaline water splitting. The resultant PC-700-10 honeycomb carbon catalyst exhibits the superior </span></span></span>electrocatalysis<span> for oxygen evolution owning to its high specific surface area of 52.0 m</span></span></span><sup>2</sup> g<sup>−1</sup><span><span>, suitable micro- and meso-pores, electron-withdrawing pyridinic-N moiety and appropriate balance between hydrophilicity and </span>electroconductivity<span><span>. Theoretical calculations reveal that the largest energy barrier of forming ∗OOH limits the OER<span> rate and ∗OH oxidation generates the energetically more favorable </span></span>epoxide intermediate. This finding opens the way to construct the hopeful metal-free OER electrocatalysts via regulating their intrinsic structure, and inspires the applications of waste biomass in the energy-correlated fields.</span></span></div></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":null,"pages":null},"PeriodicalIF":4.8000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Natural Science: Materials International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1002007124001564","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Developing the efficient and low-cost electrocatalysts derived from biomass is a desired solution to address economy and sustainability challenges of hydrogen production from water electrolysis due to utilizing metal-based catalysts. Herein, the peeled cornstalk-derived porous carbon plates synthesized by salt template-assisted high-temperature pyrolysis are utilized as self-supported metal-free electrocatalysts to unravel the oxygen evolution activity for alkaline water splitting. The resultant PC-700-10 honeycomb carbon catalyst exhibits the superior electrocatalysis for oxygen evolution owning to its high specific surface area of 52.0 m2 g−1, suitable micro- and meso-pores, electron-withdrawing pyridinic-N moiety and appropriate balance between hydrophilicity and electroconductivity. Theoretical calculations reveal that the largest energy barrier of forming ∗OOH limits the OER rate and ∗OH oxidation generates the energetically more favorable epoxide intermediate. This finding opens the way to construct the hopeful metal-free OER electrocatalysts via regulating their intrinsic structure, and inspires the applications of waste biomass in the energy-correlated fields.
期刊介绍:
Progress in Natural Science: Materials International provides scientists and engineers throughout the world with a central vehicle for the exchange and dissemination of basic theoretical studies and applied research of advanced materials. The emphasis is placed on original research, both analytical and experimental, which is of permanent interest to engineers and scientists, covering all aspects of new materials and technologies, such as, energy and environmental materials; advanced structural materials; advanced transportation materials, functional and electronic materials; nano-scale and amorphous materials; health and biological materials; materials modeling and simulation; materials characterization; and so on. The latest research achievements and innovative papers in basic theoretical studies and applied research of material science will be carefully selected and promptly reported. Thus, the aim of this Journal is to serve the global materials science and technology community with the latest research findings.
As a service to readers, an international bibliography of recent publications in advanced materials is published bimonthly.