{"title":"Comprehensive hydrogen storage properties of free-V Ti1-xZrxMn0.9Cr0.7Fe0.1 alloys with different Zr substitution content","authors":"","doi":"10.1016/j.pnsc.2024.07.011","DOIUrl":null,"url":null,"abstract":"<div><div>Hydrogen has been widely recognized as a promising new renewable energy source. Developing safe and efficient hydrogen storage technologies is crucial for scaling up hydrogen energy applications. AB<sub>2</sub>-type Ti–Mn-based hydrogen storage alloys have excellent kinetic and activation properties, but their comprehensive hydrogen storage performance, especially the hydrogen storage capacity, platform pressure, and cycling stability of low-cost Ti–Mn-based alloys without V, needs to be further optimized. Hence, the hydrogen storage properties of the Ti<sub>1-<em>x</em></sub>Zr<sub><em>x</em></sub>Mn<sub>0.9</sub>Cr<sub>0</sub><sub>.</sub><sub>7</sub>Fe<sub>0.1</sub> (<em>x</em> = 0.05, 0.16, 0.20, 0.25) were systematically studied. All of the series alloys contained a single C14-type Laves phase structure. Increasing the substitution of Zr for Ti resulted in higher hydrogen storage capacities and lower plateau pressures. Notably, the effective hydrogen storage capacity of <em>x</em> = 0.16 alloy is significantly higher than that of the other alloys, and its platform pressure is the most suitable. This alloy achieved a hydrogen content of 1.8 wt% and demonstrated excellent cycling stability, retaining 98.6 % of its capacity after 100 cycles. This study provides a theoretical guideline for optimizing the properties of low-cost TiMn-based alloys without V.</div></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":null,"pages":null},"PeriodicalIF":4.8000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Natural Science: Materials International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1002007124001606","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Hydrogen has been widely recognized as a promising new renewable energy source. Developing safe and efficient hydrogen storage technologies is crucial for scaling up hydrogen energy applications. AB2-type Ti–Mn-based hydrogen storage alloys have excellent kinetic and activation properties, but their comprehensive hydrogen storage performance, especially the hydrogen storage capacity, platform pressure, and cycling stability of low-cost Ti–Mn-based alloys without V, needs to be further optimized. Hence, the hydrogen storage properties of the Ti1-xZrxMn0.9Cr0.7Fe0.1 (x = 0.05, 0.16, 0.20, 0.25) were systematically studied. All of the series alloys contained a single C14-type Laves phase structure. Increasing the substitution of Zr for Ti resulted in higher hydrogen storage capacities and lower plateau pressures. Notably, the effective hydrogen storage capacity of x = 0.16 alloy is significantly higher than that of the other alloys, and its platform pressure is the most suitable. This alloy achieved a hydrogen content of 1.8 wt% and demonstrated excellent cycling stability, retaining 98.6 % of its capacity after 100 cycles. This study provides a theoretical guideline for optimizing the properties of low-cost TiMn-based alloys without V.
期刊介绍:
Progress in Natural Science: Materials International provides scientists and engineers throughout the world with a central vehicle for the exchange and dissemination of basic theoretical studies and applied research of advanced materials. The emphasis is placed on original research, both analytical and experimental, which is of permanent interest to engineers and scientists, covering all aspects of new materials and technologies, such as, energy and environmental materials; advanced structural materials; advanced transportation materials, functional and electronic materials; nano-scale and amorphous materials; health and biological materials; materials modeling and simulation; materials characterization; and so on. The latest research achievements and innovative papers in basic theoretical studies and applied research of material science will be carefully selected and promptly reported. Thus, the aim of this Journal is to serve the global materials science and technology community with the latest research findings.
As a service to readers, an international bibliography of recent publications in advanced materials is published bimonthly.