Utilization of GO-CS-AgNP nanocomposite for organic pollutant removal from tannery wastewater: A sustainable approach

Q1 Environmental Science
Ismat Zerin , Md. Elias Uddin , Md Ashikur Rahaman Noyon , Md. Enamul Hasan Zahin , Ibrahim M. Maafa , Ayman Yousef
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Abstract

The leather industry, often criticized for its substantial contribution to environmental pollution, has frequently overlooked the removal of organic contaminants from its wastewater. In response, this study aimed to revolutionize the treatment of tannery effluent by fabricating GO-CS-AgNP nanocomposite with noticeable adsorption efficiency for organic pollutants. Rigorous analysis, including XRD, TEM, SEM, FT-IR, and UV–Vis spectroscopy, provided a comprehensive understanding of the physico-chemical properties of GO-CS-AgNP nanocomposite. To optimize its adsorption performance, several parameters were carefully considered, including pH levels, optimal dosage, and contact time respectively. Surprisingly, employing just 0.12 g/L of the nanocomposite and 50 min of stirring at a pH of 6.0 produced highly promising adsorption results of pollutants, as evidenced by UV–Vis Spectroscopy at 450 nm. Notably, GC–MS analysis revealed an impressive 94.05 % removal of total organic pollutants, coupled with substantial reductions of 85.94 and 62.63 % in BOD and COD, respectively. Furthermore, the nanocomposite exhibited efficacy in removing potentially toxic metals. The findings of the study underscored the adherence of GO-CS-AgNP nanocomposite to the Freundlich isotherm model and a pseudo-2nd order kinetic reaction, establishing it as a sustainable and effective solution for minimizing pollution in the leather industry without compromising the environment, representing a significant leap toward more environmentally conscious tannery practices.

Abstract Image

利用 GO-CS-AgNP 纳米复合材料去除制革废水中的有机污染物:一种可持续的方法
制革行业因其对环境污染的巨大贡献而经常受到批评,但却经常忽视去除废水中的有机污染物。为此,本研究旨在通过制备对有机污染物具有显著吸附效率的 GO-CS-AgNP 纳米复合材料,彻底改变制革废水的处理方法。通过 XRD、TEM、SEM、FT-IR 和 UV-Vis 光谱等严格的分析,我们对 GO-CS-AgNP 纳米复合材料的物理化学性质有了全面的了解。为了优化其吸附性能,研究人员仔细考虑了几个参数,包括 pH 值、最佳用量和接触时间。令人惊讶的是,在 pH 值为 6.0 的条件下,仅使用 0.12 克/升的纳米复合材料并搅拌 50 分钟,就能产生非常理想的污染物吸附效果,这一点在 450 纳米的紫外可见光谱中得到了证明。值得注意的是,气相色谱-质谱分析表明,总有机污染物的去除率高达 94.05%,生化需氧量和化学需氧量也分别大幅降低了 85.94% 和 62.63%。此外,纳米复合材料还具有去除潜在有毒金属的功效。研究结果表明,GO-CS-AgNP 纳米复合材料符合 Freundlich 等温线模型和伪 2 阶动力学反应,可作为一种可持续的有效解决方案,在不损害环境的前提下最大限度地减少皮革行业的污染,是制革工厂朝着更具环保意识的方向迈出的重要一步。
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来源期刊
Environmental Nanotechnology, Monitoring and Management
Environmental Nanotechnology, Monitoring and Management Environmental Science-Water Science and Technology
CiteScore
13.00
自引率
0.00%
发文量
132
审稿时长
48 days
期刊介绍: Environmental Nanotechnology, Monitoring and Management is a journal devoted to the publication of peer reviewed original research on environmental nanotechnologies, monitoring studies and management for water, soil , waste and human health samples. Critical review articles, short communications and scientific policy briefs are also welcome. The journal will include all environmental matrices except air. Nanomaterials were suggested as efficient cost-effective and environmental friendly alternative to existing treatment materials, from the standpoints of both resource conservation and environmental remediation. The journal aims to receive papers in the field of nanotechnology covering; Developments of new nanosorbents for: •Groundwater, drinking water and wastewater treatment •Remediation of contaminated sites •Assessment of novel nanotechnologies including sustainability and life cycle implications Monitoring and Management papers should cover the fields of: •Novel analytical methods applied to environmental and health samples •Fate and transport of pollutants in the environment •Case studies covering environmental monitoring and public health •Water and soil prevention and legislation •Industrial and hazardous waste- legislation, characterisation, management practices, minimization, treatment and disposal •Environmental management and remediation
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