Impactor identification with spallogenic Cr isotopes: The Wabar impact craters (Saudi Arabia)

IF 2.2 4区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS
Aryavart Anand, Klaus Mezger, Beda Hofmann
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引用次数: 0

Abstract

Precise measurements of Cr isotopic composition of terrestrial impactites have successfully provided evidence for the presence of extraterrestrial material and have, in some cases, allowed the identification of the type of impactor responsible for the formation of the impact structure. The high Cr abundance in most meteorite groups aids in detecting extraterrestrial contamination while their distinct isotopic compositions can help with the identification of the nature of the projectile. However, this common approach of detection and identification of extraterrestrial contamination using mass-independent 53Cr and 54Cr variations fails when the impactor type is an iron meteorite because of their low Cr abundances (which are in a similar range to terrestrial rocks). The present study demonstrates the viability of a spallogenic Cr contribution in iron meteorites (resulting from their long cosmic ray exposure times), which compensates for their low Cr abundances and facilitates the identification of iron-meteoritic contamination in terrestrial impactites. Thus, it broadens the scope of impactors (and impactites) that can be investigated using mass-independent Cr isotopes from solely chondrites and primitive achondrites to include iron meteorites. The Wabar impact craters are an optimal candidate for this study, characterized by low weathering, diverse impactites, partial meteorite survival, substantial impactor material contamination, and a felsic target lithology with low background Cr concentration. The Cr isotopic composition of the Wabar background sand, which represents the target lithology, is indistinguishable from the terrestrial Cr isotopic composition range, whereas the Wabar iron meteorites show coupled spallogenic excesses in ε53Cr and ε54Cr. The Cr isotopic compositions of Wabar impactites show resolved deviations from the terrestrial Cr isotopic composition, thereby indicating the presence of Wabar meteoritic contamination. Moreover, the study demonstrates that even an impactor with a non-carbonaceous chondritic origin, such as a IIIAB iron meteorite, can have a carbonaceous chondrite-like signature in ε54Cr anomalies due to spallogenic Cr contamination. The study advocates for a comprehensive investigation combining platinum group elements and Cr (and/or Ni, Ru) isotopes to accurately characterize impactor types.

Abstract Image

利用成岩铬同位素识别撞击坑:瓦巴尔撞击坑(沙特阿拉伯)
对陆地撞击岩的铬同位素组成的精确测量成功地提供了地外物质存在的证据,在某些情况下,还能确定形成撞击结构的撞击物的类型。大多数陨石群的铬丰度较高,有助于探测地外污染,而其独特的同位素组成则有助于确定抛射物的性质。然而,当撞击物类型为铁陨石时,这种利用与质量无关的 53Cr 和 54Cr 变化来探测和识别地外污染的常见方法就失效了,因为它们的铬丰度较低(与陆地岩石的铬丰度范围相似)。本研究证明了铁陨石(因其宇宙射线暴露时间长)中的成陨铬贡献是可行的,它弥补了铁陨石的低铬丰度,并有助于识别陆地撞击岩中的铁陨石污染。因此,它扩大了可使用来自纯软玉体和原始隐陨石的质量无关铬同位素来研究的撞击物(和撞击岩)的范围,将铁陨石也包括在内。瓦巴尔撞击坑是这项研究的最佳候选地,其特点是风化程度低、撞击岩多样、部分陨石存活、撞击物物质污染严重,以及目标岩性为长英岩且本底铬浓度较低。代表目标岩性的瓦巴尔背景砂的铬同位素组成与陆地铬同位素组成范围无异,而瓦巴尔铁陨石则显示出ε53Cr和ε54Cr的耦合成矿过量。瓦巴尔撞击岩的铬同位素组成与陆地铬同位素组成有明显偏差,这表明瓦巴尔陨石污染的存在。此外,该研究还表明,即使是非碳质软玉起源的撞击物,如 IIIAB 铁陨石,也可能由于成岩的铬污染而在ε54Cr 异常中具有碳质软玉的特征。该研究主张结合铂族元素和铬(和/或镍、钌)同位素进行全面调查,以准确地确定撞击器类型的特征。
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来源期刊
Meteoritics & Planetary Science
Meteoritics & Planetary Science 地学天文-地球化学与地球物理
CiteScore
3.90
自引率
31.80%
发文量
121
审稿时长
3 months
期刊介绍: First issued in 1953, the journal publishes research articles describing the latest results of new studies, invited reviews of major topics in planetary science, editorials on issues of current interest in the field, and book reviews. The publications are original, not considered for publication elsewhere, and undergo peer-review. The topics include the origin and history of the solar system, planets and natural satellites, interplanetary dust and interstellar medium, lunar samples, meteors, and meteorites, asteroids, comets, craters, and tektites. Our authors and editors are professional scientists representing numerous disciplines, including astronomy, astrophysics, physics, geophysics, chemistry, isotope geochemistry, mineralogy, earth science, geology, and biology. MAPS has subscribers in over 40 countries. Fifty percent of MAPS'' readers are based outside the USA. The journal is available in hard copy and online.
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