Effect of plasma discharge pulse length for GaN film crystallinity on sapphire substrate by high density convergent plasma sputtering device

Itsuki Misono, T. Motomura, T. Tabaru, Masato Uehara, Tetsuya Okuyama
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Abstract

Plasma discharge pulse length (tPLength) was investigated for its impact on the crystallinity of GaN films deposited on a sapphire substrate using a high-density convergent plasma sputtering device (CPSD). The study covered tPLength values from 1 to 200 ms, maintaining the substrate temperature at 200 °C. GaN films showed preferential orientation along the (0002) plane for all tPLength settings. X-ray diffraction analysis revealed a heteroepitaxial-like growth pattern with a sixfold symmetric diffraction pattern corresponding to GaN{10−10} planes. At a tPLength of 200 ms, the full width at half maximum of the rocking curve at GaN (0002) diffraction angle decreased to 1.6°. Optimizing the deposition rate per plasma discharge pulse with CPSD indicated the importance of selecting an optimal tPLength for achieving desirable crystalline properties in GaN film sputtering deposition.
等离子体放电脉冲长度对高密度聚合等离子体溅射装置在蓝宝石衬底上形成氮化镓薄膜结晶度的影响
研究了等离子体放电脉冲长度(tPLength)对使用高密度聚合等离子体溅射装置(CPSD)沉积在蓝宝石基底上的氮化镓薄膜结晶度的影响。研究涵盖了 1 到 200 ms 的 tPLength 值,基底温度保持在 200 °C。在所有 tPLength 设置下,GaN 薄膜都显示出沿 (0002) 平面的优先取向。X 射线衍射分析显示了一种异外延生长模式,其六倍对称衍射模式与 GaN{10-10} 平面相对应。当 tPLength 为 200 ms 时,GaN(0002)衍射角处的摇摆曲线半最大值全宽降至 1.6°。利用 CPSD 优化每个等离子体放电脉冲的沉积速率表明,在 GaN 薄膜溅射沉积过程中,选择最佳的 tPLength 对于获得理想的结晶特性非常重要。
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