N. L. Bazyakina, A. O. Kochina, E. V. Baranov, I. L. Fedushkin
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引用次数: 0
Abstract
The reaction of the complex [(dpp-bian)2−Yb2+(THF)4] (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with two molar equivalents of 1,3-bis(pyridin-4-yl)propane (bpp) in tetrahydrofuran (THF) afforded the 2D coordination polymer [{(dpp-bian)Yb(bpp)2} • 3 THF]n (1). The reaction of [(dpp-bian)2−Yb2+(DME)2] with phenazine (phz) gave the dimeric complex [{(dpp-bian)Yb(DME)}2(μ-η3:η3-phz)] • 2 DME (2), in which two cationic {(dpp-bian)Yb(DME)} units are connected via a bridging phenazine dianion. Compounds 1 and 2 were characterized by elemental analysis and IR spectroscopy. Their molecular structures were determined by single-crystal X-ray diffraction analysis. Thermal stability of compound 1 was studied by thermogravimetric analysis.
期刊介绍：
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.
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