Polycrystalline Methylammonium–Lead Bromide Perovskite Films for Photonic Metasurfaces

IF 0.6 4区 材料科学 Q4 CRYSTALLOGRAPHY
G. A. Yurasik, I. V. Kasyanova, V. V. Artemov, A. A. Ezhov, I. S. Pavlov, A. A. Antonov, G. Long, M. V. Gorkunov
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Abstract

Polycrystalline films of organic–inorganic perovskite semiconductors are promising as a base for designing functional optical metasurfaces. The requirements to their structural quality, thickness uniformity, homogeneity, and absence of defects are much more stringent than those for perovskite films used in photovoltaics. The results of searching for the optimal conditions of one-stage synthesis of methylammonium-lead bromide films by spin coating are reported, and successful preparation of subwavelength optical gratings based on them using focused ion beam (FIB) processing is described. The measured light transmission spectra demonstrated excellent optical quality of the gratings and confirmed the possibility of forming semiconductor photonic metasurfaces with submicron periodicity and high-Q dielectric resonances.

Abstract Image

用于光子金属表面的多晶甲基溴化铅铵过氧化物薄膜
摘要 有机-无机包晶半导体多晶薄膜是设计功能性光学超表面的基础,具有广阔的前景。对其结构质量、厚度均匀性、均质性和无缺陷的要求要比光伏领域使用的包晶薄膜严格得多。本文报告了通过旋涂法寻找一步合成溴化甲基铵铅薄膜的最佳条件的结果,并介绍了使用聚焦离子束(FIB)工艺在此基础上成功制备亚波长光栅的情况。测量的透光光谱表明光栅具有极佳的光学质量,并证实了形成具有亚微米周期性和高Q介电共振的半导体光子元表面的可能性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Crystallography Reports
Crystallography Reports 化学-晶体学
CiteScore
1.10
自引率
28.60%
发文量
96
审稿时长
4-8 weeks
期刊介绍: Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.
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