Synthesis and Optoelectronic Properties of Threaded BODIPYs.

IF 2.5 4区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

ChemistryOpen Pub Date : 2024-07-23 DOI:10.1002/open.202400196

Matthieu Hicguet, Olivier Mongin, Yann R Leroux, Thierry Roisnel, Fabienne Berrée, Yann Trolez

引用次数: 0

Abstract

We report on the synthesis of two new threaded BODIPYs 5 and 6 in good yields using boron as a gathering atom and a macrocycle with a 2,2'-biphenol unit. In addition to usual techniques, they were characterized by X-ray crystallography. Their electrochemical and optical properties were investigated. In particular, both compounds are highly emissive with photoluminescence quantum yields of 54 and 81 % respectively. In addition, they both show a high photostability.

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螺纹 BODIPYs 的合成与光电特性。

我们报告了利用硼作为聚集原子和一个具有 2,2'- 联苯酚单元的大环，以良好的产率合成了两种新的螺纹 BODIPYs 5 和 6。除常规技术外，还利用 X 射线晶体学对它们进行了表征。此外，还研究了它们的电化学和光学特性。特别是，这两种化合物都具有很高的发射性，光致发光量子产率分别为 54% 和 81%。此外，它们还具有很高的光稳定性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

ChemistryOpen CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

4.80

自引率

4.30%

发文量

143

审稿时长

1 months

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