Ze-Le Chen, Qiang-Qiang Li, Armido Studer, Jun Xuan
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引用次数: 0
Abstract
Nitroso compounds have emerged as highly valuable reaction partners or reagents in organic synthesis due to their rich reactivity. The versatile profile of these compounds allows them to function as electrophiles, nucleophiles, diradicals, and radical acceptors in diverse transformations. In recent years, notable progress has been made in harnessing photochemical reactions with nitroso compounds to prepare N,O-containing structures using mild and eco-friendly conditions. Various nitroso compounds like nitrosoarenes, acyloxy nitroso compounds, N-nitrosoamines and nitrites have received significant attention for their ability to introduce NO moieties into complex molecules that are otherwise difficult to access. In this review, we provide an overview of the recent advancements in the visible light-induced conversion of nitroso compounds, with particular emphasis on their role as bifunctional reagents and acceptors of radicals, carbenes and nitrenes.
亚硝基化合物因其丰富的反应活性而成为有机合成中极具价值的反应伙伴或试剂。亚硝基化合物的多功能性使其在各种转化过程中可充当亲电体、亲核体、二元自由基和自由基受体。近年来,利用亚硝基化合物的光化学反应,在温和、环保的条件下制备含 N、O 结构方面取得了显著进展。各种亚硝基化合物,如亚硝基烯烃、酰氧基亚硝基化合物、N-亚硝基胺和亚硝酸盐,因其能够将 NO 分子引入到其他方法难以进入的复杂分子中而备受关注。在本综述中,我们将概述最近在可见光诱导亚硝基化合物转化方面取得的进展,并特别强调亚硝基化合物作为双功能试剂和自由基、羰基和亚硝基烯的受体所发挥的作用。
期刊介绍:
Science China Chemistry, co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China and published by Science China Press, publishes high-quality original research in both basic and applied chemistry. Indexed by Science Citation Index, it is a premier academic journal in the field.
Categories of articles include:
Highlights. Brief summaries and scholarly comments on recent research achievements in any field of chemistry.
Perspectives. Concise reports on thelatest chemistry trends of interest to scientists worldwide, including discussions of research breakthroughs and interpretations of important science and funding policies.
Reviews. In-depth summaries of representative results and achievements of the past 5–10 years in selected topics based on or closely related to the research expertise of the authors, providing a thorough assessment of the significance, current status, and future research directions of the field.