Investigation of the ageing behaviour of multiple reused polypropylene binding twines

Philippe du Maire, Felix Gärtner, Matthias H. Deckert, Michael Johlitz, Andreas Öchsner
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Abstract

Climate change is one of the significant challenges of the 21st century. To achieve climate goals a change in plastic waste management needs to be implemented. This research examines the potential of thermo-mechanical recycling of plastic waste, focusing on agricultural binding twines made from polypropylene. Old binding twines from agriculture were collected and recycled with a twin screw extruder. The ageing behaviour of the recyclate in terms of multiple recycling is examined in detail with tensile tests and melt volume rate measurements. The findings indicate a general degradation in mechanical properties and a decrease in viscosity due to molecular chain scission. Despite these degradations, the material remains processable, indicating the potential for continued recycling loops.

Abstract Image

多次重复使用聚丙烯捆扎麻绳的老化行为调查
气候变化是 21 世纪的重大挑战之一。为了实现气候目标,必须改变塑料废物的管理方式。本研究以聚丙烯制成的农业捆扎用麻绳为重点,探讨了塑料废物热机械回收利用的潜力。研究人员收集了旧的农用捆扎麻绳,并用双螺杆挤出机进行回收。通过拉伸试验和熔体容积率测量,详细研究了多次回收的回收物的老化行为。研究结果表明,由于分子链断裂,机械性能普遍下降,粘度降低。尽管出现了这些退化现象,但材料仍然可以加工,这表明它具有继续循环利用的潜力。
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