{"title":"Three metal organic frameworksof Cd(II) with tri(4‐carboxybenzyl) amine and their photoluminescence properties","authors":"Xiang He, Shuang Dong, Jie Jiang","doi":"10.1002/zaac.202400096","DOIUrl":null,"url":null,"abstract":"Utilizing the flexible carboxylic acid ligand, tri(4‐carboxybenzyl) amine (H3L), three new coordination polymers Na[Cd(L)]n·3nH2O (1), [Cd(HL)(4,4’‐bipy)0.5(H2O)]n (2) (4,4’‐bipy = 4,4’‐bipyridine) and [Cd(HL)(2,2’‐bipy)]n (3) (2,2’‐bipy = 2,2’‐bipyridine) have been successfully synthesized. Compounds 1 and 2 are all 2D structures with (3,6) 2‐nodal as kgd topology, while compound 3 is a 1D chain structure. The powder X‐ray diffraction and the thermal stabilities were studied for 1‐3. In addition, the solid‐state luminescence properties of compounds 1‐3 were also tested at room temperature, indicating their application prospects in fluorescent materials.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"50 7","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für anorganische und allgemeine Chemie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/zaac.202400096","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Utilizing the flexible carboxylic acid ligand, tri(4‐carboxybenzyl) amine (H3L), three new coordination polymers Na[Cd(L)]n·3nH2O (1), [Cd(HL)(4,4’‐bipy)0.5(H2O)]n (2) (4,4’‐bipy = 4,4’‐bipyridine) and [Cd(HL)(2,2’‐bipy)]n (3) (2,2’‐bipy = 2,2’‐bipyridine) have been successfully synthesized. Compounds 1 and 2 are all 2D structures with (3,6) 2‐nodal as kgd topology, while compound 3 is a 1D chain structure. The powder X‐ray diffraction and the thermal stabilities were studied for 1‐3. In addition, the solid‐state luminescence properties of compounds 1‐3 were also tested at room temperature, indicating their application prospects in fluorescent materials.