Composite cathode Gd0.2Ce0.8O1.9–SrFe1−xTixO3-δ for Nicotiana tabacum-derived carbon fuel-based direct carbon fuel cell

Abstract

As an electrochemical device that converts the chemical energy of fuel directly into electrical energy, the fuel cell is a new alternative technology that uses fuel from renewable sources and generates power for sustainable development and energy security. Among various types of fuel cells, the direct carbon fuel cell (DCFC) has higher efficiency because carbon fuel has higher energy density than liquid or gas fuel. However, the current development of DCFCs is still limited by the sluggish activity of the cathode reaction. In this study, a new composite cathode made of Gd_0.2Ce_0.8O_1.9 (GDC) and SrFe_1−xTi_xO_3–δ (SFT) is developed for a Nicotiana tabacum-derived carbon fuel-based DCFC. The structural, optical, and electrochemical properties of the materials are systematically evaluated. X-ray diffraction analysis results show a cubic structure of GDC and cubic perovskite phase of SFT in the sample, with crystallite sizes of 37 and 15 nm, respectively. Ultraviolet–visible spectroscopy reveals an indirect band gap which exhibits a red shift. Fourier transform infrared spectroscopy confirms the presence of Ce–O, Sr–Ti–O, and Fe–O functional groups in all the samples. Scanning electron microscopy analysis shows the morphology and particle size of the materials. The sample Gd_0.2Ce_0.8O_2-δ–SrFe_0.96Ti_0.04O_1.9 exhibits the highest electrical conductivity of 4.96 S cm⁻¹ in an oxygen atmosphere at 600 °C and a higher power density of 40 mW cm⁻² at 600 °C compared to other samples using Nicotiana tabacum carbon fuel. These findings indicate that the developed composite cathode is an efficient cathode for low-temperature DCFCs.