Improvement of the environmental fatigue resistance of epoxy-based electrical steel laminates by pre-treatment of the substrate

IF 3.2 3区 材料科学 Q2 ENGINEERING, CHEMICAL
Marc Ninou Codina , Gernot M. Wallner , Robert Pugstaller , Gabriel Riedl , Bernhard Strauß , Martin Rosner
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Abstract

Electrical generators or engines are based on full surface bonded steel plies. Temperature control is of high relevance to achieve reduced heat dissipations along with improved efficiency. This paper evaluated the effect of service relevant operating conditions (i.e., cooling agents, elevated service temperature and fatigue stresses) on the delamination behavior of electrical steel laminates on specimen and lab level. Therefore, a linear elastic fracture mechanics method and a set-up suitable for superimposed environmental and cyclic fatigue testing was implemented and employed. Two electrical steel laminate configurations were investigated. Pre-treated and un-treated sheets were double side coated with an epoxy varnish. Further, a catalyst was applied on both sides of the coated sheets made from the pre-treated substrate. Double cantilever beam specimens were manufactured by stacking and laminating 6 coated substrates. The fractured surfaces of the fatigue tested specimen were characterized by laser confocal microscopy and infrared spectroscopy in hemispheric reflectance mode. Threshold strain energy release rate values (Gth) ranging from 16 to 62 J/m2 were obtained depending on the investigated coated substrates and the environmental conditions. Laminates produced with pre-treated sheets and catalyst exhibited notably enhanced Gth and decreased rates of crack propagation within the stable crack growth regime. A similar crack growth behavior was ascertained in hot air or oil-based cooling agent. The crossover point of the temperature dependent Gth values was indicative for the glass transition temperature of the adhesives. The fractured surfaces presented mainly cohesive failure at higher strain energy release rate values followed by mixed cohesive and interfacial failure when approaching to the threshold regime.

通过对基材进行预处理提高环氧基电工钢层压板的抗环境疲劳性能
发电机或发动机以全表面粘结钢层为基础。温度控制对于减少散热和提高效率具有重要意义。本文在试样和实验室水平上评估了与使用相关的操作条件(即冷却剂、使用温度升高和疲劳应力)对电工钢层压板分层行为的影响。因此,本文采用了线性弹性断裂力学方法和适合叠加环境和循环疲劳测试的装置。研究了两种电工钢层压板结构。预处理和未处理板材双面涂有环氧清漆。此外,还在由预处理基材制成的涂层板材两侧涂上催化剂。双悬臂梁试样由 6 块涂层基板堆叠层压而成。通过激光共聚焦显微镜和半球反射模式下的红外光谱,对疲劳测试试样的断裂表面进行了表征。阈值应变能量释放率(Gth)从 16 到 62 J/m2 不等,取决于所研究的涂层基板和环境条件。使用预处理板材和催化剂生产的层压板在稳定的裂纹生长机制下,Gth 值明显提高,裂纹扩展速率明显降低。在热空气或油性冷却剂中,也发现了类似的裂纹生长行为。与温度相关的 Gth 值的交叉点表明了粘合剂的玻璃化转变温度。当应变能释放率值较高时,断裂表面主要表现为内聚破坏,当接近阈值时,则表现为内聚和界面混合破坏。
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来源期刊
International Journal of Adhesion and Adhesives
International Journal of Adhesion and Adhesives 工程技术-材料科学:综合
CiteScore
6.90
自引率
8.80%
发文量
200
审稿时长
8.3 months
期刊介绍: The International Journal of Adhesion and Adhesives draws together the many aspects of the science and technology of adhesive materials, from fundamental research and development work to industrial applications. Subject areas covered include: interfacial interactions, surface chemistry, methods of testing, accumulation of test data on physical and mechanical properties, environmental effects, new adhesive materials, sealants, design of bonded joints, and manufacturing technology.
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