Tuning the dimensionality in chiral and racemic organic/tin hybrids with halides†

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2024-07-18 DOI:10.1039/D4DT01645A

Louis Caussin, Abdelaziz Jouaiti, Daniel Chartrand, W. G. Skene and Sylvie Ferlay

引用次数: 0

Abstract

Chiral 1D tin iodides EBASnI₃ were synthesized while incorporating enantiomerically pure and racemic ethylbenzylammonium (EBA) cations between the 1D shared inorganic corners. The dimensionality was reduced to 0D when replacing iodine with bromine. In all the cases, the presence of hydrogen bonds was observed between the organic part and the inorganic part, while transfer of chirality was evidenced for the EBASnI₃ enantiomerically pure compounds.

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用卤化物调节手性和外消旋有机/锡混合物的维度。

合成了手性一维碘化锡 EBASnI3，同时在一维共享无机角之间加入了对映体纯的外消旋乙基苄基铵（EBA）阳离子。当用溴取代碘时，维度降至 0D。在所有情况下，有机部分和无机部分之间都出现了氢键，而 EBASnI3 对映体纯化合物则出现了手性转移。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.