{"title":"Engineered MXene-polymer composites for water remediation: Promises, challenges and future perspective","authors":"","doi":"10.1016/j.ccr.2024.216089","DOIUrl":null,"url":null,"abstract":"<div><p>Technological innovation has enabled the development of new materials, with two-dimensional materials garnering much interest in recent years. Transition metal nitrides, oxycarbides, carbonitrides, and carbides, collectively termed MXenes, display favorable chemical and physical properties. A striking feature of MXenes is their diverse elemental makeups and ability to have multiple surface functional groups, providing a versatile platform to create novel composites. Indeed, many MXene-polymer composites have already been made using different polymers, allowing fine-tuning for intended uses. These materials have been used in a wide spectrum of environmental research, being applied in processes such as photocatalysis, electrochemical water splitting, contaminant removal, desalination, CO<sub>2</sub> reduction, hydrogen evolution, and sensing. This review comprehensively surveys recent progress in MXene-polymer composites, including fabrication approaches, and modification strategies. Moreover, it systematically categorizes the applications of MXene-polymer composites for different water treatment applications such as desalination, removing heavy metals, dyes, pharmaceutical residuals, hazardous materials, natural organic matters, and oil–water separation among others. Finally, it addresses challenges, limitations, and future directions for these composites, while introducing potential ways to enhance MXenes to further expand MXene-polymer composite utilities going forward.</p></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":null,"pages":null},"PeriodicalIF":20.3000,"publicationDate":"2024-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854524004351","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Technological innovation has enabled the development of new materials, with two-dimensional materials garnering much interest in recent years. Transition metal nitrides, oxycarbides, carbonitrides, and carbides, collectively termed MXenes, display favorable chemical and physical properties. A striking feature of MXenes is their diverse elemental makeups and ability to have multiple surface functional groups, providing a versatile platform to create novel composites. Indeed, many MXene-polymer composites have already been made using different polymers, allowing fine-tuning for intended uses. These materials have been used in a wide spectrum of environmental research, being applied in processes such as photocatalysis, electrochemical water splitting, contaminant removal, desalination, CO2 reduction, hydrogen evolution, and sensing. This review comprehensively surveys recent progress in MXene-polymer composites, including fabrication approaches, and modification strategies. Moreover, it systematically categorizes the applications of MXene-polymer composites for different water treatment applications such as desalination, removing heavy metals, dyes, pharmaceutical residuals, hazardous materials, natural organic matters, and oil–water separation among others. Finally, it addresses challenges, limitations, and future directions for these composites, while introducing potential ways to enhance MXenes to further expand MXene-polymer composite utilities going forward.
期刊介绍:
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.