{"title":"Ternary Cu2MX4 (CMX)-based nanoarchitectonics: Chemistry, synthesis, and biomedical applications","authors":"","doi":"10.1016/j.ccr.2024.216052","DOIUrl":null,"url":null,"abstract":"<div><p>Owing to their elemental abundance and unique bandgap, ternary transition metal chalcogenides (TMCs) have recently attracted significant attention from researchers. Among various TMCs, Cu<sub>2</sub>MX<sub>4</sub> (M = Mo, and W; X = S, and Se, shortly denoted as CMX) species possess distinct advantages, such as tunable chemical composition, resultant diverse morphologies (structure, size, and shape), excellent biocompatibility, exceptional degradability, unique catalytic performance, and considerable <em>in vivo</em> elimination. Considering these outstanding morphological attributes and desirable physicochemical features, this article explicitly reviews recent advancements and the latest breakthroughs of different CMX-based nanoarchitectures for biomedicine. Initially, we discuss the chemistry and relevant properties offered by elements in the composites. Then, a brief note is given on different CMX-based nanoarchitectures. Further, we present various synthesis strategies for generating different structures, highlighting their altered morphology and the factors affecting various formulation parameters. Further, the possible effects offered by these CMX-based nanoarchitectures are explored in different fields of biomedicine. Finally, we summarize the article with an interesting outlook on their clinical translation.</p></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":null,"pages":null},"PeriodicalIF":20.3000,"publicationDate":"2024-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854524003989","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Owing to their elemental abundance and unique bandgap, ternary transition metal chalcogenides (TMCs) have recently attracted significant attention from researchers. Among various TMCs, Cu2MX4 (M = Mo, and W; X = S, and Se, shortly denoted as CMX) species possess distinct advantages, such as tunable chemical composition, resultant diverse morphologies (structure, size, and shape), excellent biocompatibility, exceptional degradability, unique catalytic performance, and considerable in vivo elimination. Considering these outstanding morphological attributes and desirable physicochemical features, this article explicitly reviews recent advancements and the latest breakthroughs of different CMX-based nanoarchitectures for biomedicine. Initially, we discuss the chemistry and relevant properties offered by elements in the composites. Then, a brief note is given on different CMX-based nanoarchitectures. Further, we present various synthesis strategies for generating different structures, highlighting their altered morphology and the factors affecting various formulation parameters. Further, the possible effects offered by these CMX-based nanoarchitectures are explored in different fields of biomedicine. Finally, we summarize the article with an interesting outlook on their clinical translation.
期刊介绍:
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.