Synthesis of Carbon Dots via Microwave-Assisted Process: Specific Sensing of Fe(III) and Antibacterial Activity.

IF 3.1 4区 化学 Q2 BIOCHEMICAL RESEARCH METHODS
Journal of Fluorescence Pub Date : 2025-06-01 Epub Date: 2024-07-13 DOI:10.1007/s10895-024-03845-z
Hosimin Selvaraj, Ganapathy Bruntha, Andivelu Ilangovan
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引用次数: 0

Abstract

Carbon dots synthesized from a renewable and sustainable source of biomass have greater attention in the nanomaterial research field. In the present study, we adopted a facile and green synthesis of carbon dots from bio waste of pumpkin seeds using a one-pot microwave-assisted carbonization method. The synthesized carbon dots exhibit excellent photoluminescence properties with a bright blue emission peak at 399 nm and fluorescence quantum yield was about 9.5%. The optical properties and structure of carbon dots were examined using various spectroscopy techniques and the synthesized carbon practical size was about 4.37 nm and possessed good solubility in water. Carbon dots were used for the detection of Ferric ions in the water bodies and the interaction between Fe3+ ions and carbon dots was evaluated by fluorescence spectroscopy techniques. This method is a simple and selective detection of Fe3+ in the aqueous medium. Interestingly carbon dots also show good antibacterial activity at a very low concentration (1 mg/L) for effective control of E. coli 93% and Pseudomonas aeruginosa (81%), within 12 h.

Abstract Image

通过微波辅助工艺合成碳点:铁(III)的特异性传感和抗菌活性。
利用可再生、可持续的生物质合成碳点在纳米材料研究领域受到更多关注。在本研究中,我们采用一锅微波辅助碳化法,从南瓜籽生物废料中简便、绿色地合成了碳点。合成的碳点具有优异的光致发光性能,在 399 纳米波长处具有明亮的蓝色发射峰,荧光量子产率约为 9.5%。利用各种光谱技术检测了碳点的光学性质和结构,合成的碳实用尺寸约为 4.37 nm,在水中具有良好的溶解性。碳点被用于检测水体中的铁离子,并通过荧光光谱技术评估了 Fe3+ 离子与碳点之间的相互作用。这种方法可以简单、选择性地检测水介质中的 Fe3+。有趣的是,碳点在极低浓度(1 毫克/升)下也显示出良好的抗菌活性,在 12 小时内可有效控制 93% 的大肠杆菌和 81% 的铜绿假单胞菌。
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来源期刊
Journal of Fluorescence
Journal of Fluorescence 化学-分析化学
CiteScore
4.60
自引率
7.40%
发文量
203
审稿时长
5.4 months
期刊介绍: Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.
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