Effects of Different Concentrations of Weak Acid Fracturing Fluid on the Microstructure of Coal

Abstract

As a crucial factor that influences the hydraulic fracturing effectiveness of coal seams, fracturing fluids have garnered increasing attention. Among them, acid fracturing fluids have demonstrated positive impact on the pore transformation of coal, but high-strength acid fracturing fluids can cause corrosion damage to mechanical equipment. In this study, we employed acetic acid to formulate four types of weak acid fracturing fluids with varying concentrations and conducted soaking experiments. We analyzed the changes in the physical and chemical structure of coal samples before and after treatment using Fourier-transform infrared spectroscopy and X-ray diffraction analysis. The changes in the pore structure of coal samples before and after treatment were characterized by nitrogen adsorption and scanning electron microscopy. Our findings indicate the following: (1) The effects of different concentrations of acetic acid fracturing fluid on functional groups and microcrystalline structure vary. The 5% concentration fracturing fluid had the most significant impact on the organic structure of coal samples, with decreases in the area of hydroxyl structure, aliphatic structure, and oxygen-containing structure of 2.97%, 1.37%, and 0.68%, respectively. The 6% concentration fracturing fluid had the most significant impact on crystal structure, leading to a high degree of recrystallization and a fragile crystal network structure. (2) Fracturing fluids with concentrations below 7% can increase the number of mesopores and simplify the pore structure, while concentrations above 7% can lead to an increase in micropores and a more complex pore structure. (3) After the action of fracturing fluid, carbonate minerals are dissolved, and the pores of coal samples increase. However, excessively high concentrations of acetic acid fracturing fluid can facilitate shedding of mineral particles and block some pore channels, worsening the connectivity between pores. (4) The octadecylamine acetate formed by the combination of octadecylamine and acetic acid develops as a partial film on the surface of a coal body, reducing the roughness of the fracture surface and facilitating the flow of the fracturing fluid. Our findings provide theoretical support for the preparation and selection of weak acid fracturing fluids.